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题名: Reagent orbital alignment effect in chemiluminescence reactions Ca(P-1(1))+CH3X (X = Cl, I)
作者: Ding, GW;  Sun, WZ;  Yang, WS;  Xu, DL;  He, GZ;  Lou, NQ
刊名: MOLECULAR PHYSICS
发表日期: 1999-05-10
卷: 96, 期:9, 页:1349-1354
收录类别: SCI
文章类型: Article
WOS标题词: Science & Technology ;  Physical Sciences
类目[WOS]: Physics, Atomic, Molecular & Chemical
研究领域[WOS]: Physics
英文摘要: Reagent orbital alignment effects in chemiluminescence reactions Ca(P-1(1)) + CH3X (X = Cl, I) are studied in a beam-gas apparatus. Stronger alignment dependence is found in the reaction Ca(P-1(1)) + CH3CI. For an ideal case, a simple expression is derived to calculate the reagent alignment sensitivity factor. This analysis shows that the primary reasons for the different alignment dependence between Ca(P-1(1)) + CH3CI and Ca(P-1(1)) + CH3I lie in two facts: one is the larger reaction radius for the latter reaction, and the other is the larger potential splitting V-Pi-V-Sigma for the former reaction.
关键词[WOS]: ANGULAR-MOMENTUM ;  ATOMIC-COLLISIONS ;  CROSSED-BEAM ;  POLARIZATION ;  DEPENDENCE ;  GEOMETRY ;  BR
语种: 英语
WOS记录号: WOS:000080416400006
Citation statistics: 
内容类型: 期刊论文
URI标识: http://cas-ir.dicp.ac.cn/handle/321008/138648
Appears in Collections:中国科学院大连化学物理研究所_期刊论文

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作者单位: 1.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Mol React Dynam, Dalian 116023, Peoples R China

Recommended Citation:
Ding, GW,Sun, WZ,Yang, WS,et al. Reagent orbital alignment effect in chemiluminescence reactions Ca(P-1(1))+CH3X (X = Cl, I)[J]. MOLECULAR PHYSICS,1999,96(9):1349-1354.
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