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Reagent orbital alignment effect in chemiluminescence reactions Ca(P-1(1))+CH3X (X = Cl, I)
Ding, GW; Sun, WZ; Yang, WS; Xu, DL; He, GZ; Lou, NQ
刊名MOLECULAR PHYSICS
1999-05-10
96期:9页:1349-1354
收录类别SCI
文章类型Article
WOS标题词Science & Technology ; Physical Sciences
类目[WOS]Physics, Atomic, Molecular & Chemical
研究领域[WOS]Physics
关键词[WOS]ANGULAR-MOMENTUM ; ATOMIC-COLLISIONS ; CROSSED-BEAM ; POLARIZATION ; DEPENDENCE ; GEOMETRY ; BR
英文摘要Reagent orbital alignment effects in chemiluminescence reactions Ca(P-1(1)) + CH3X (X = Cl, I) are studied in a beam-gas apparatus. Stronger alignment dependence is found in the reaction Ca(P-1(1)) + CH3CI. For an ideal case, a simple expression is derived to calculate the reagent alignment sensitivity factor. This analysis shows that the primary reasons for the different alignment dependence between Ca(P-1(1)) + CH3CI and Ca(P-1(1)) + CH3I lie in two facts: one is the larger reaction radius for the latter reaction, and the other is the larger potential splitting V-Pi-V-Sigma for the former reaction.
语种英语
WOS记录号WOS:000080416400006
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被引频次:2[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://cas-ir.dicp.ac.cn/handle/321008/138648
专题中国科学院大连化学物理研究所
作者单位Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Mol React Dynam, Dalian 116023, Peoples R China
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GB/T 7714
Ding, GW,Sun, WZ,Yang, WS,et al. Reagent orbital alignment effect in chemiluminescence reactions Ca(P-1(1))+CH3X (X = Cl, I)[J]. MOLECULAR PHYSICS,1999,96(9):1349-1354.
APA Ding, GW,Sun, WZ,Yang, WS,Xu, DL,He, GZ,&Lou, NQ.(1999).Reagent orbital alignment effect in chemiluminescence reactions Ca(P-1(1))+CH3X (X = Cl, I).MOLECULAR PHYSICS,96(9),1349-1354.
MLA Ding, GW,et al."Reagent orbital alignment effect in chemiluminescence reactions Ca(P-1(1))+CH3X (X = Cl, I)".MOLECULAR PHYSICS 96.9(1999):1349-1354.
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