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Ab initio/Rice-Ramsperger-Kassel-Marcus approach to carbon nitride formation: CH3NH2 decomposition
Zhang, RQ; Han, KL; Zhu, RS; Lee, CS; Lee, ST
Source PublicationCHEMICAL PHYSICS LETTERS
2000-04-21
Volume321Issue:1-2Pages:101-105
Indexed BySCI
SubtypeArticle
WOS HeadingsScience & Technology ; Physical Sciences
WOS SubjectChemistry, Physical ; Physics, Atomic, Molecular & Chemical
WOS Research AreaChemistry ; Physics
WOS KeywordSOLIDS ; DIAMOND ; STABILITY ; C3N4
AbstractAn approach of combination of ab initio calculation with Rice-Ramsperger-Kassel-Marcus theory has been applied to the study of carbon nitride formation. The energetic characteristics and decomposition of one important intermediate CH3NH2 used in chemical vapor deposition (CVD) of carbon nitride thin film have been studied over a wide range of pressure and temperature. The calculated rate constants for three possible decomposition channels of the CH3NH2 depends strongly on the reaction temperature and pressure. The high rate constants for the CH3NH2 decomposition at high temperature might be responsible for the HCN or CNH formation in CVD of carbon nitride thin film. (C) 2000 Elsevier Science B.V. All rights reserved.
Language英语
WOS IDWOS:000086634300017
Citation statistics
Cited Times:8[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://cas-ir.dicp.ac.cn/handle/321008/138673
Collection中国科学院大连化学物理研究所
Affiliation1.City Univ Hong Kong, Ctr Super Diamond & Adv Films, Hong Kong, Hong Kong, Peoples R China
2.City Univ Hong Kong, Dept Phys & Mat Sci, Hong Kong, Hong Kong, Peoples R China
3.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Mol React Dynam, Dalian 116023, Peoples R China
Recommended Citation
GB/T 7714
Zhang, RQ,Han, KL,Zhu, RS,et al. Ab initio/Rice-Ramsperger-Kassel-Marcus approach to carbon nitride formation: CH3NH2 decomposition[J]. CHEMICAL PHYSICS LETTERS,2000,321(1-2):101-105.
APA Zhang, RQ,Han, KL,Zhu, RS,Lee, CS,&Lee, ST.(2000).Ab initio/Rice-Ramsperger-Kassel-Marcus approach to carbon nitride formation: CH3NH2 decomposition.CHEMICAL PHYSICS LETTERS,321(1-2),101-105.
MLA Zhang, RQ,et al."Ab initio/Rice-Ramsperger-Kassel-Marcus approach to carbon nitride formation: CH3NH2 decomposition".CHEMICAL PHYSICS LETTERS 321.1-2(2000):101-105.
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