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题名: Active catalyst for the hydrodechlorination of perchlorobenzene
作者: Gao, Y;  Wang, FD;  Liao, SJ;  Yu, DR;  Sun, N
关键词: perchlorobenzene ;  hydrodechlorination ;  PVP-supported Pd-Co catalyst ;  NaBH4
刊名: REACTIVE & FUNCTIONAL POLYMERS
发表日期: 2000-04-14
卷: 44, 期:1, 页:65-69
收录类别: SCI
文章类型: Article
WOS标题词: Science & Technology ;  Physical Sciences ;  Technology
类目[WOS]: Chemistry, Applied ;  Engineering, Chemical ;  Polymer Science
研究领域[WOS]: Chemistry ;  Engineering ;  Polymer Science
英文摘要: Palladium catalysts have been used in the hydrodechlorination of perchlorobenzene under mild conditions. PdCl2 is not very active for this reaction. However, when PdCl2 is supported on PVP (polyvinyl pyrrolidone), it exhibits a high activity. Pd-Co supported on PVP displays a bimetallic synergic effect and gives higher catalytic activity. The catalytic activity can be increased further by using NaBH4 to reduce the catalyst instead of H-2 prior to use. (C) 2000 Elsevier Science B.V. All rights reserved.
关键词[WOS]: BIMETALLIC PALLADIUM-RUTHENIUM ;  SELECTIVE HYDROGENATION ;  ORGANIC HALIDES ;  MILD CONDITIONS ;  ATMOSPHERIC-PRESSURE ;  ALLYL HALIDES ;  CARBONYLATION ;  FORMATE ;  METAL ;  HYDRODEHALOGENATION
语种: 英语
WOS记录号: WOS:000086478000008
Citation statistics: 
内容类型: 期刊论文
URI标识: http://cas-ir.dicp.ac.cn/handle/321008/138686
Appears in Collections:中国科学院大连化学物理研究所_期刊论文

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作者单位: 1.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Peoples R China

Recommended Citation:
Gao, Y,Wang, FD,Liao, SJ,et al. Active catalyst for the hydrodechlorination of perchlorobenzene[J]. REACTIVE & FUNCTIONAL POLYMERS,2000,44(1):65-69.
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