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Hydrogenation behavior of highly active nanometric magnesium powders doped with titanocene
Fan, YH; Zhang, SQ; Liao, SJ; Xu, J; Wang, FD
关键词Nanometric Magnesium Powders Doped With Titanocene Thermal Decomposition Of Magnesium Anthracene Hydrogenation
刊名CHINESE JOURNAL OF INORGANIC CHEMISTRY
2000-07-01
16期:4页:661-664
收录类别SCI
文章类型Article
WOS标题词Science & Technology ; Physical Sciences
类目[WOS]Chemistry, Inorganic & Nuclear
研究领域[WOS]Chemistry
关键词[WOS]THERMAL-DECOMPOSITION ; CATALYTIC SYNTHESIS ; ANTHRACENE SYSTEMS ; REAGENTS ; HYDRIDE
英文摘要Titanocene(CpTiCl3) has been found to be an efficient dopant for the hydrogenation of nano metric magnesium powders. These magnesium powders are generated by the thermal decomposition of magnesium anthracene . 3THF at 90 similar to 150 degrees C under vacuum. They can uptake hydrogen to form magnesium hydride even at 185 degrees C with a hydrogenation rate much higher than those of the undoped ones under normal pressure. The order of the hydrogenation reaction with respect to the nanometric magnesium surface area is one.
语种英语
WOS记录号WOS:000089166300021
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文献类型期刊论文
条目标识符http://cas-ir.dicp.ac.cn/handle/321008/138717
专题中国科学院大连化学物理研究所
作者单位1.Liaoning Normal Univ, Dept Chem, Dalian 116029, Peoples R China
2.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Peoples R China
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Fan, YH,Zhang, SQ,Liao, SJ,et al. Hydrogenation behavior of highly active nanometric magnesium powders doped with titanocene[J]. CHINESE JOURNAL OF INORGANIC CHEMISTRY,2000,16(4):661-664.
APA Fan, YH,Zhang, SQ,Liao, SJ,Xu, J,&Wang, FD.(2000).Hydrogenation behavior of highly active nanometric magnesium powders doped with titanocene.CHINESE JOURNAL OF INORGANIC CHEMISTRY,16(4),661-664.
MLA Fan, YH,et al."Hydrogenation behavior of highly active nanometric magnesium powders doped with titanocene".CHINESE JOURNAL OF INORGANIC CHEMISTRY 16.4(2000):661-664.
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