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题名: Hydrogenation behavior of highly active nanometric magnesium powders doped with titanocene
作者: Fan, YH;  Zhang, SQ;  Liao, SJ;  Xu, J;  Wang, FD
关键词: nanometric magnesium powders ;  doped with titanocene ;  thermal decomposition of magnesium anthracene ;  hydrogenation
刊名: CHINESE JOURNAL OF INORGANIC CHEMISTRY
发表日期: 2000-07-01
卷: 16, 期:4, 页:661-664
收录类别: SCI
文章类型: Article
WOS标题词: Science & Technology ;  Physical Sciences
类目[WOS]: Chemistry, Inorganic & Nuclear
研究领域[WOS]: Chemistry
英文摘要: Titanocene(CpTiCl3) has been found to be an efficient dopant for the hydrogenation of nano metric magnesium powders. These magnesium powders are generated by the thermal decomposition of magnesium anthracene . 3THF at 90 similar to 150 degrees C under vacuum. They can uptake hydrogen to form magnesium hydride even at 185 degrees C with a hydrogenation rate much higher than those of the undoped ones under normal pressure. The order of the hydrogenation reaction with respect to the nanometric magnesium surface area is one.
关键词[WOS]: THERMAL-DECOMPOSITION ;  CATALYTIC SYNTHESIS ;  ANTHRACENE SYSTEMS ;  REAGENTS ;  HYDRIDE
语种: 英语
WOS记录号: WOS:000089166300021
Citation statistics: 
内容类型: 期刊论文
URI标识: http://cas-ir.dicp.ac.cn/handle/321008/138717
Appears in Collections:中国科学院大连化学物理研究所_期刊论文

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作者单位: 1.Liaoning Normal Univ, Dept Chem, Dalian 116029, Peoples R China
2.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Peoples R China

Recommended Citation:
Fan, YH,Zhang, SQ,Liao, SJ,et al. Hydrogenation behavior of highly active nanometric magnesium powders doped with titanocene[J]. CHINESE JOURNAL OF INORGANIC CHEMISTRY,2000,16(4):661-664.
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