DICP OpenIR
Formation, photodissociation and structure of chromium/phosphorus binary cluster ions
Han, CY; Zhao, X; Zhang, X; Gao, Z; Zhu, QH
刊名RAPID COMMUNICATIONS IN MASS SPECTROMETRY
2000
14期:14页:1255-1259
收录类别SCI
文章类型Article
WOS标题词Science & Technology ; Physical Sciences ; Technology
类目[WOS]Chemistry, Analytical ; Spectroscopy
研究领域[WOS]Chemistry ; Spectroscopy
关键词[WOS]FRAGMENTATION ; TITANIUM
英文摘要Chromium/phosphorus binary cluster ions, [CrnPm](+/-) , produced by laser (532nm) ablation on a tablet of well-mixed chromium and red phosphorus powder, were studied with a home-built tandem time-of-flight (TOF) mass spectrometer. The clusters thus formed are mostly rich in phosphorus. There is an odd-even oscillation in the intensity of the [CrPm](+) series, i.e, the mass peaks of even m are higher than those of odd m, The peaks of [CrP4]+ and [CrP8](+) are especially prominent, which may be ascribed to the specific stability of P-4 sub-structures. There are also some intense peaks in the spectrum assigned to [Cr3P8](+), [Cr4P9](+), [Cr5P11](+), [Cr6P12](+), [Cr8P14](+) clusters, etc., which have stable compositions. The stability of these species is consistent with a simple qualitative electronic structure model, in which the valence electrons of P are filled into the d orbitals of Cr, The photodissociation of some cluster ions was also studied. DFT calculations were performed on three small cluster ions to provide some insight into their structures. Copyright (C) 2000 John Wiley & Sons, Ltd.
语种英语
WOS记录号WOS:000088407300014
引用统计
被引频次:8[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://cas-ir.dicp.ac.cn/handle/321008/138739
专题中国科学院大连化学物理研究所
作者单位Chinese Acad Sci, Inst Chem, Ctr Mol Sci, State Key Lab Mol React Dynam, Beijing 100080, Peoples R China
推荐引用方式
GB/T 7714
Han, CY,Zhao, X,Zhang, X,et al. Formation, photodissociation and structure of chromium/phosphorus binary cluster ions[J]. RAPID COMMUNICATIONS IN MASS SPECTROMETRY,2000,14(14):1255-1259.
APA Han, CY,Zhao, X,Zhang, X,Gao, Z,&Zhu, QH.(2000).Formation, photodissociation and structure of chromium/phosphorus binary cluster ions.RAPID COMMUNICATIONS IN MASS SPECTROMETRY,14(14),1255-1259.
MLA Han, CY,et al."Formation, photodissociation and structure of chromium/phosphorus binary cluster ions".RAPID COMMUNICATIONS IN MASS SPECTROMETRY 14.14(2000):1255-1259.
条目包含的文件
条目无相关文件。
个性服务
推荐该条目
保存到收藏夹
查看访问统计
导出为Endnote文件
谷歌学术
谷歌学术中相似的文章
[Han, CY]的文章
[Zhao, X]的文章
[Zhang, X]的文章
百度学术
百度学术中相似的文章
[Han, CY]的文章
[Zhao, X]的文章
[Zhang, X]的文章
必应学术
必应学术中相似的文章
[Han, CY]的文章
[Zhao, X]的文章
[Zhang, X]的文章
相关权益政策
暂无数据
收藏/分享
所有评论 (0)
暂无评论
 

除非特别说明,本系统中所有内容都受版权保护,并保留所有权利。