DICP OpenIR
The effect of the coating solvent on chiral recognition ability by coated chiral stationary phases
Chen, XM; Yang, L; Zou, HF
关键词Solvent Coating Microcrystalline Triacetylcellulose Chiral Recognition
刊名CHINESE JOURNAL OF ANALYTICAL CHEMISTRY
2000-07-01
28期:7页:879-882
收录类别SCI
文章类型Article
WOS标题词Science & Technology ; Physical Sciences
类目[WOS]Chemistry, Analytical
研究领域[WOS]Chemistry
英文摘要The microcrystalline triacetylcellulose (MCTA) was synthesized under heterogeneous acetylation conditions, using microcrystalline cellulose material. MCTA was dissolved in dichloromethane and chloroform with the addition of different organic solvents and coated on underivatised silica gel by evaporation under vacuum to prepare the chiral stationary phases (CSPs) for high-performance liquid chromatography. Most of the CSPs show good chiral recognition ability for the resolution of trans-stilbene oxide and praziquantel in our experiments. It was found that aromatic compounds and organic acids affect the cu value when they were added into dichloromethane as coating solvents. It was observed that CSPs prepared with dichloromethane + 10% nitrobenzene lost its chiral recognition for trans-stilbene oxide with 100% ethanol as mobile phase. The best resolution of enantiomers was obtained on CSPs prepared with dichloromethane + 30% phenol as coating solvent.
语种英语
WOS记录号WOS:000088489300021
引用统计
被引频次:1[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://cas-ir.dicp.ac.cn/handle/321008/138741
专题中国科学院大连化学物理研究所
作者单位Chinese Acad Sci, Dalian Inst Chem Phys, Natl Chromatog Res & Anal Ctr, Dalian 116012, Peoples R China
推荐引用方式
GB/T 7714
Chen, XM,Yang, L,Zou, HF. The effect of the coating solvent on chiral recognition ability by coated chiral stationary phases[J]. CHINESE JOURNAL OF ANALYTICAL CHEMISTRY,2000,28(7):879-882.
APA Chen, XM,Yang, L,&Zou, HF.(2000).The effect of the coating solvent on chiral recognition ability by coated chiral stationary phases.CHINESE JOURNAL OF ANALYTICAL CHEMISTRY,28(7),879-882.
MLA Chen, XM,et al."The effect of the coating solvent on chiral recognition ability by coated chiral stationary phases".CHINESE JOURNAL OF ANALYTICAL CHEMISTRY 28.7(2000):879-882.
条目包含的文件
条目无相关文件。
个性服务
推荐该条目
保存到收藏夹
查看访问统计
导出为Endnote文件
谷歌学术
谷歌学术中相似的文章
[Chen, XM]的文章
[Yang, L]的文章
[Zou, HF]的文章
百度学术
百度学术中相似的文章
[Chen, XM]的文章
[Yang, L]的文章
[Zou, HF]的文章
必应学术
必应学术中相似的文章
[Chen, XM]的文章
[Yang, L]的文章
[Zou, HF]的文章
相关权益政策
暂无数据
收藏/分享
所有评论 (0)
暂无评论
 

除非特别说明,本系统中所有内容都受版权保护,并保留所有权利。