DICP OpenIR
Effect of functional monomer on chiral separation ability of molecular imprinted chiral stationary phase
Wang, JF; Zhou, LM; Liu, XL; Wang, QH; Zhu, DQ
KeywordMolecule Imprinted Polymer Basic Functional Monomer Combined Functional Monomers Chiral Stationary Phase Amino Acid Derivatives
Source PublicationACTA CHIMICA SINICA
2000
Volume58Issue:3Pages:351-355
Indexed BySCI
SubtypeArticle
WOS HeadingsScience & Technology ; Physical Sciences
WOS SubjectChemistry, Multidisciplinary
WOS Research AreaChemistry
WOS KeywordPOLYMERS ; RECOGNITION ; RESOLUTION
AbstractThe effect of functional monomer on chiral separation ability of the non - covalent molecular imprinted chiral stationary phase was investigated systematically. It was found that there was compatibleness between the functional monomer and the template molecules. Strong hydrogen bond and ionic interaction could be formed between the amide group and carboxyl group in the amino acid derivatives and acrylamide and 2 vinylpyridine, which made the imprinting effect of the combined functional monomers AM + 2 - VP more evident. The competing solvent acetic acid showed great influence on the non - covalent interaction between the analyte and the functional groups of molecular imprinted polymer (MIP). Ionic interaction and hydrogen bending between amide group and carboxyl group in the analyte and the functional groups of MIP were weakened by increasing the concentration of the competing solvent acetic acid, therefore both the capacity factor, chiral selectivity faster and resolution decreased.
Language英语
WOS IDWOS:000087090300019
Citation statistics
Cited Times:2[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://cas-ir.dicp.ac.cn/handle/321008/138744
Collection中国科学院大连化学物理研究所
AffiliationChinese Acad Sci, Dalian Inst Chem Phys, Dalian 116012, Peoples R China
Recommended Citation
GB/T 7714
Wang, JF,Zhou, LM,Liu, XL,et al. Effect of functional monomer on chiral separation ability of molecular imprinted chiral stationary phase[J]. ACTA CHIMICA SINICA,2000,58(3):351-355.
APA Wang, JF,Zhou, LM,Liu, XL,Wang, QH,&Zhu, DQ.(2000).Effect of functional monomer on chiral separation ability of molecular imprinted chiral stationary phase.ACTA CHIMICA SINICA,58(3),351-355.
MLA Wang, JF,et al."Effect of functional monomer on chiral separation ability of molecular imprinted chiral stationary phase".ACTA CHIMICA SINICA 58.3(2000):351-355.
Files in This Item:
There are no files associated with this item.
Related Services
Recommend this item
Bookmark
Usage statistics
Export to Endnote
Google Scholar
Similar articles in Google Scholar
[Wang, JF]'s Articles
[Zhou, LM]'s Articles
[Liu, XL]'s Articles
Baidu academic
Similar articles in Baidu academic
[Wang, JF]'s Articles
[Zhou, LM]'s Articles
[Liu, XL]'s Articles
Bing Scholar
Similar articles in Bing Scholar
[Wang, JF]'s Articles
[Zhou, LM]'s Articles
[Liu, XL]'s Articles
Terms of Use
No data!
Social Bookmark/Share
All comments (0)
No comment.
 

Items in the repository are protected by copyright, with all rights reserved, unless otherwise indicated.