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Effect of functional monomer on chiral separation ability of molecular imprinted chiral stationary phase
Wang, JF; Zhou, LM; Liu, XL; Wang, QH; Zhu, DQ
关键词Molecule Imprinted Polymer Basic Functional Monomer Combined Functional Monomers Chiral Stationary Phase Amino Acid Derivatives
刊名ACTA CHIMICA SINICA
2000
58期:3页:351-355
收录类别SCI
文章类型Article
WOS标题词Science & Technology ; Physical Sciences
类目[WOS]Chemistry, Multidisciplinary
研究领域[WOS]Chemistry
关键词[WOS]POLYMERS ; RECOGNITION ; RESOLUTION
英文摘要The effect of functional monomer on chiral separation ability of the non - covalent molecular imprinted chiral stationary phase was investigated systematically. It was found that there was compatibleness between the functional monomer and the template molecules. Strong hydrogen bond and ionic interaction could be formed between the amide group and carboxyl group in the amino acid derivatives and acrylamide and 2 vinylpyridine, which made the imprinting effect of the combined functional monomers AM + 2 - VP more evident. The competing solvent acetic acid showed great influence on the non - covalent interaction between the analyte and the functional groups of molecular imprinted polymer (MIP). Ionic interaction and hydrogen bending between amide group and carboxyl group in the analyte and the functional groups of MIP were weakened by increasing the concentration of the competing solvent acetic acid, therefore both the capacity factor, chiral selectivity faster and resolution decreased.
语种英语
WOS记录号WOS:000087090300019
引用统计
被引频次:2[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://cas-ir.dicp.ac.cn/handle/321008/138744
专题中国科学院大连化学物理研究所
作者单位Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116012, Peoples R China
推荐引用方式
GB/T 7714
Wang, JF,Zhou, LM,Liu, XL,et al. Effect of functional monomer on chiral separation ability of molecular imprinted chiral stationary phase[J]. ACTA CHIMICA SINICA,2000,58(3):351-355.
APA Wang, JF,Zhou, LM,Liu, XL,Wang, QH,&Zhu, DQ.(2000).Effect of functional monomer on chiral separation ability of molecular imprinted chiral stationary phase.ACTA CHIMICA SINICA,58(3),351-355.
MLA Wang, JF,et al."Effect of functional monomer on chiral separation ability of molecular imprinted chiral stationary phase".ACTA CHIMICA SINICA 58.3(2000):351-355.
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