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题名: Catalytic selective hydrogenation of cinnamaldehyde to hydrocinnamaldehyde
作者: Zhang, YK;  Liao, SJ;  Xu, Y;  Yu, DR
关键词: selective hydrogenation ;  bimetallic catalysts ;  hydrocinnamaldehyde ;  cinnamaldehyde
刊名: APPLIED CATALYSIS A-GENERAL
发表日期: 2000-02-14
卷: 192, 期:2, 页:247-251
收录类别: SCI
文章类型: Article
WOS标题词: Science & Technology ;  Physical Sciences ;  Life Sciences & Biomedicine
类目[WOS]: Chemistry, Physical ;  Environmental Sciences
研究领域[WOS]: Chemistry ;  Environmental Sciences & Ecology
英文摘要: The catalytic selectivity and activity of the catalyst PdCl2 can be improved significantly by using PPh3 as a ligand and NaBH4 as a reducing agent in the selective hydrogenation of cinnamaldehyde (CAL) to hydrocinnamaldehyde (HCAL) under atmospheric pressure. Adding a second transition metal component [NiCl2, Ni(OAc)(2), Fe(acac)(3), Co(OAc)(2)] to the catalyst can improve its selectivity further. PdCl2-0.5Co(OAc)(2)-PPh3 reduced by NaBH4 is the best catalyst. (C) 2000 Elsevier Science B.V. All rights reserved.
关键词[WOS]: BIMETALLIC PALLADIUM-RUTHENIUM ;  NICKEL BORIDE ;  ALPHA,BETA-UNSATURATED ALDEHYDES ;  COMPLEXES ;  COLLOIDS ;  SPECTROSCOPY ;  REDUCTION ;  CLUSTERS ;  SOLVENT
语种: 英语
WOS记录号: WOS:000084977300011
Citation statistics: 
内容类型: 期刊论文
URI标识: http://cas-ir.dicp.ac.cn/handle/321008/138761
Appears in Collections:中国科学院大连化学物理研究所_期刊论文

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作者单位: 1.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Peoples R China

Recommended Citation:
Zhang, YK,Liao, SJ,Xu, Y,et al. Catalytic selective hydrogenation of cinnamaldehyde to hydrocinnamaldehyde[J]. APPLIED CATALYSIS A-GENERAL,2000,192(2):247-251.
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