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Catalytic selective hydrogenation of cinnamaldehyde to hydrocinnamaldehyde
Zhang, YK; Liao, SJ; Xu, Y; Yu, DR
关键词Selective Hydrogenation Bimetallic Catalysts Hydrocinnamaldehyde Cinnamaldehyde
刊名APPLIED CATALYSIS A-GENERAL
2000-02-14
192期:2页:247-251
收录类别SCI
文章类型Article
WOS标题词Science & Technology ; Physical Sciences ; Life Sciences & Biomedicine
类目[WOS]Chemistry, Physical ; Environmental Sciences
研究领域[WOS]Chemistry ; Environmental Sciences & Ecology
关键词[WOS]BIMETALLIC PALLADIUM-RUTHENIUM ; NICKEL BORIDE ; ALPHA,BETA-UNSATURATED ALDEHYDES ; COMPLEXES ; COLLOIDS ; SPECTROSCOPY ; REDUCTION ; CLUSTERS ; SOLVENT
英文摘要The catalytic selectivity and activity of the catalyst PdCl2 can be improved significantly by using PPh3 as a ligand and NaBH4 as a reducing agent in the selective hydrogenation of cinnamaldehyde (CAL) to hydrocinnamaldehyde (HCAL) under atmospheric pressure. Adding a second transition metal component [NiCl2, Ni(OAc)(2), Fe(acac)(3), Co(OAc)(2)] to the catalyst can improve its selectivity further. PdCl2-0.5Co(OAc)(2)-PPh3 reduced by NaBH4 is the best catalyst. (C) 2000 Elsevier Science B.V. All rights reserved.
语种英语
WOS记录号WOS:000084977300011
引用统计
被引频次:33[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://cas-ir.dicp.ac.cn/handle/321008/138761
专题中国科学院大连化学物理研究所
作者单位Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Peoples R China
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Zhang, YK,Liao, SJ,Xu, Y,et al. Catalytic selective hydrogenation of cinnamaldehyde to hydrocinnamaldehyde[J]. APPLIED CATALYSIS A-GENERAL,2000,192(2):247-251.
APA Zhang, YK,Liao, SJ,Xu, Y,&Yu, DR.(2000).Catalytic selective hydrogenation of cinnamaldehyde to hydrocinnamaldehyde.APPLIED CATALYSIS A-GENERAL,192(2),247-251.
MLA Zhang, YK,et al."Catalytic selective hydrogenation of cinnamaldehyde to hydrocinnamaldehyde".APPLIED CATALYSIS A-GENERAL 192.2(2000):247-251.
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