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Thermodynamic study on separation of molecular imprinting chiral stationary phase
Wang, JF; Zhou, LM; Liu, XL; Wang, QH; Zhu, DQ
关键词Molecular Imprinting Polymer Chiral Stationary Phase Chiral Separation Mechanism Thermodynamic Parameter
刊名CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE
2000-06-01
21期:6页:930-933
收录类别SCI
文章类型Article
WOS标题词Science & Technology ; Physical Sciences
类目[WOS]Chemistry, Multidisciplinary
研究领域[WOS]Chemistry
关键词[WOS]FUNCTIONAL MONOMERS ; POLYMERS ; RECOGNITION ; RESOLUTION
英文摘要The effect of temperature on the chiral separation of the molecular imprinting polymer was investigated and the thermodynamic parameters were calculated, It was found that the chiral separation process was enthalpy-controlled. Increasing the temperature decreases the capacity factor and chiral selectivity factor. The interactions between the analyte and the molecular imprinting chiral stationary phase were both non-specific and specific, and only the difference of specific interaction results in the chiral separation. The imprinting cavities affected the thermodynamic parameters dramatically, The rebinding of the imprinted molecule into the imprinting cavities was favorable in view of energy and configuration because of their best compatibleness.
语种英语
WOS记录号WOS:000087772500026
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被引频次:9[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://cas-ir.dicp.ac.cn/handle/321008/138774
专题中国科学院大连化学物理研究所
作者单位Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116012, Peoples R China
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GB/T 7714
Wang, JF,Zhou, LM,Liu, XL,et al. Thermodynamic study on separation of molecular imprinting chiral stationary phase[J]. CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE,2000,21(6):930-933.
APA Wang, JF,Zhou, LM,Liu, XL,Wang, QH,&Zhu, DQ.(2000).Thermodynamic study on separation of molecular imprinting chiral stationary phase.CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE,21(6),930-933.
MLA Wang, JF,et al."Thermodynamic study on separation of molecular imprinting chiral stationary phase".CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE 21.6(2000):930-933.
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