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Synthesis of Ti-MCM-41 using colloidal silica and titanium trichloride - III. Catalytic activity of Ti-MCM-41 molecular sieve
Yu, JQ; Li, C; Xu, L; Li, MJ; Xin, Q; Liu, ZM
关键词Mesoporous Molecular Sieve Ti-mcm-41 Styrene Alpha-methyl Styrene Cyclohexene Selective Oxidation Epoxidation
刊名CHINESE JOURNAL OF CATALYSIS
2001-07-01
22期:4页:335-338
收录类别SCI
文章类型Article
WOS标题词Science & Technology ; Physical Sciences ; Technology
类目[WOS]Chemistry, Applied ; Chemistry, Physical ; Engineering, Chemical
研究领域[WOS]Chemistry ; Engineering
关键词[WOS]MFI TOPOLOGY
英文摘要The catalytic properties of the Ti-MCM-41 molecular sieve synthesized from colloidal silica and TiCl3 were tested in the epoxidation of styrene, alpha -methyl styrene and cyclohexene using 30% H2O2 solution as the oxidant. The catalysts show excellent catalytic properties and the substrate conversion and the product selectivity are comparable with those in the case of Ti-MCM-41 synthesized from organic precursors. The results obtained from the three olefins with different structure indicate that the main procedure of the oxidation of olefins with terminal C=C bond is the oxidative cleavage, while that of cyclohexene is the epoxidation.
语种英语
WOS记录号WOS:000170470800006
引用统计
文献类型期刊论文
条目标识符http://cas-ir.dicp.ac.cn/handle/321008/138842
专题中国科学院大连化学物理研究所
作者单位Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Peoples R China
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GB/T 7714
Yu, JQ,Li, C,Xu, L,et al. Synthesis of Ti-MCM-41 using colloidal silica and titanium trichloride - III. Catalytic activity of Ti-MCM-41 molecular sieve[J]. CHINESE JOURNAL OF CATALYSIS,2001,22(4):335-338.
APA Yu, JQ,Li, C,Xu, L,Li, MJ,Xin, Q,&Liu, ZM.(2001).Synthesis of Ti-MCM-41 using colloidal silica and titanium trichloride - III. Catalytic activity of Ti-MCM-41 molecular sieve.CHINESE JOURNAL OF CATALYSIS,22(4),335-338.
MLA Yu, JQ,et al."Synthesis of Ti-MCM-41 using colloidal silica and titanium trichloride - III. Catalytic activity of Ti-MCM-41 molecular sieve".CHINESE JOURNAL OF CATALYSIS 22.4(2001):335-338.
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