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题名: Synthesis of Ti-MCM-41 using colloidal silica and titanium trichloride - III. Catalytic activity of Ti-MCM-41 molecular sieve
作者: Yu, JQ;  Li, C;  Xu, L;  Li, MJ;  Xin, Q;  Liu, ZM
关键词: mesoporous molecular sieve ;  Ti-MCM-41 ;  styrene ;  alpha-methyl styrene ;  cyclohexene ;  selective oxidation ;  epoxidation
刊名: CHINESE JOURNAL OF CATALYSIS
发表日期: 2001-07-01
卷: 22, 期:4, 页:335-338
收录类别: SCI
文章类型: Article
WOS标题词: Science & Technology ;  Physical Sciences ;  Technology
类目[WOS]: Chemistry, Applied ;  Chemistry, Physical ;  Engineering, Chemical
研究领域[WOS]: Chemistry ;  Engineering
英文摘要: The catalytic properties of the Ti-MCM-41 molecular sieve synthesized from colloidal silica and TiCl3 were tested in the epoxidation of styrene, alpha -methyl styrene and cyclohexene using 30% H2O2 solution as the oxidant. The catalysts show excellent catalytic properties and the substrate conversion and the product selectivity are comparable with those in the case of Ti-MCM-41 synthesized from organic precursors. The results obtained from the three olefins with different structure indicate that the main procedure of the oxidation of olefins with terminal C=C bond is the oxidative cleavage, while that of cyclohexene is the epoxidation.
关键词[WOS]: MFI TOPOLOGY
语种: 英语
WOS记录号: WOS:000170470800006
Citation statistics: 
内容类型: 期刊论文
URI标识: http://cas-ir.dicp.ac.cn/handle/321008/138842
Appears in Collections:中国科学院大连化学物理研究所_期刊论文

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作者单位: 1.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Peoples R China

Recommended Citation:
Yu, JQ,Li, C,Xu, L,et al. Synthesis of Ti-MCM-41 using colloidal silica and titanium trichloride - III. Catalytic activity of Ti-MCM-41 molecular sieve[J]. CHINESE JOURNAL OF CATALYSIS,2001,22(4):335-338.
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