DICP OpenIR
Applications of in situ NMR in catalytic processes of organic reactions
Han, XW; Yan, ZM; Zhang, WP; Bao, XH
刊名CURRENT ORGANIC CHEMISTRY
2001-10-01
5期:10页:1017-1037
收录类别SCI
文章类型Review
WOS标题词Science & Technology ; Physical Sciences
类目[WOS]Chemistry, Organic
研究领域[WOS]Chemistry
关键词[WOS]SOLID-STATE NMR ; ANGLE-SPINNING NMR ; METHANE DEHYDRO-AROMATIZATION ; MOLECULAR-SIEVE CATALYSTS ; TO-HYDROCARBON CHEMISTRY ; CARBON CARBON BOND ; PT-HMOR CATALYSTS ; O-XYLENE MIXTURE ; IN-SITU ; MAS NMR
英文摘要In situ MAS NMR has been demonstrated to be a superior technique for analyzing desorbed reactants, reacting adsorbates, intermediates and products. The results are useful for getting deeper insights into catalytic processes and reaction kinetics, and for revealing the mechanisms of organic reactions. The utility of in situ NMR spectroscopy has demonstrated that this technique is an important means for the studies of catalytic organic reactions. The objective of this paper is to give a review on the generation of apparatus for in situ MAS NMR experiments, and to illustrate the applications of the in situ MAS NMR techniques in various important organic reactions catalyzed by solid catalysts. The typical reactions studied by in situ MAS NMR techniques include conversion of methanol to hydrocarbons (MTG process), aromatization of methane, ethylbenzene reaction over zeolite HMOR. observation of carbenium intermediates formation, and photocatalytic organic reaction.
语种英语
WOS记录号WOS:000172120000004
引用统计
被引频次:23[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://cas-ir.dicp.ac.cn/handle/321008/138848
专题中国科学院大连化学物理研究所
作者单位Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian, Peoples R China
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GB/T 7714
Han, XW,Yan, ZM,Zhang, WP,et al. Applications of in situ NMR in catalytic processes of organic reactions[J]. CURRENT ORGANIC CHEMISTRY,2001,5(10):1017-1037.
APA Han, XW,Yan, ZM,Zhang, WP,&Bao, XH.(2001).Applications of in situ NMR in catalytic processes of organic reactions.CURRENT ORGANIC CHEMISTRY,5(10),1017-1037.
MLA Han, XW,et al."Applications of in situ NMR in catalytic processes of organic reactions".CURRENT ORGANIC CHEMISTRY 5.10(2001):1017-1037.
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