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Effects of additives on catalytic oxidation of 1-methoxy-2-propanol to methoxyacetone
Wang, JW; Zhou, N; Zhao, CX; Cao, GY; Hu, XQ
关键词Methoxy-propanol Methoxyacetone Tungsten Compound Hydrogen Peroxide Catalytic Oxidation
刊名CHINESE JOURNAL OF CATALYSIS
2001
22期:1页:87-88
收录类别SCI
文章类型Article
WOS标题词Science & Technology ; Physical Sciences ; Technology
类目[WOS]Chemistry, Applied ; Chemistry, Physical ; Engineering, Chemical
研究领域[WOS]Chemistry ; Engineering
关键词[WOS]HYDROGEN-PEROXIDE ; ALCOHOLS
英文摘要The system W-VI-H2O2 has good selectivity for methoxyacetone in oxidation of 1-methoxy-2-propanol. The effects of acid and base additives on selectivity for methoxyacetone were studied. The results showed that the acid additive, i.e. NaHSO4, was favorable to Na2WO4-H2O2 system, while the base additive NEt3 was favorable to other tungsten compounds. A 71.2% of yield of methoxyacetone with 98.9% of selectivity for methoxyacetone was obtained in Na2WO4-H2O2-NaHSO4-MeCOMe oxidation system.
语种英语
WOS记录号WOS:000170358800024
引用统计
被引频次:2[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://cas-ir.dicp.ac.cn/handle/321008/138947
专题中国科学院大连化学物理研究所
作者单位Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Peoples R China
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GB/T 7714
Wang, JW,Zhou, N,Zhao, CX,et al. Effects of additives on catalytic oxidation of 1-methoxy-2-propanol to methoxyacetone[J]. CHINESE JOURNAL OF CATALYSIS,2001,22(1):87-88.
APA Wang, JW,Zhou, N,Zhao, CX,Cao, GY,&Hu, XQ.(2001).Effects of additives on catalytic oxidation of 1-methoxy-2-propanol to methoxyacetone.CHINESE JOURNAL OF CATALYSIS,22(1),87-88.
MLA Wang, JW,et al."Effects of additives on catalytic oxidation of 1-methoxy-2-propanol to methoxyacetone".CHINESE JOURNAL OF CATALYSIS 22.1(2001):87-88.
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