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题名: The low-temperature heat capacity and thermodynamic functions of propyl tert-butyl ethers
作者: Varushchenko, RM;  Druzhinina, AI;  Churkina, AY;  Tan, ZC
刊名: RUSSIAN JOURNAL OF PHYSICAL CHEMISTRY
发表日期: 2001-08-01
卷: 75, 期:8, 页:1223-1231
收录类别: SCI
文章类型: Article
WOS标题词: Science & Technology ;  Physical Sciences
类目[WOS]: Chemistry, Physical
研究领域[WOS]: Chemistry
英文摘要: The heat capacities of n-propyl tert-butyl and isopropyl tert-butyl ethers were measured in the temperature range 10-353 K by adiabatic calorimetry. Solid phases of both compounds were found to contain metastable and stable polymorphs. Solid n-propyl tert-butyl ether also contained a vitreous component. The temperatures and enthalpies of fusion of the ethers were determined. The S-m(o) (T) - S-m(o) (0), H-m(o) (T) - H-m(o) (0), and G(m)(o) (T) - H-m(o) (0) molar thermodynamic functions and the entropies of formation of the substances in the ideal gas state at 298.15 K were calculated.
语种: 英语
WOS记录号: WOS:000170630100001
Citation statistics: 
内容类型: 期刊论文
URI标识: http://cas-ir.dicp.ac.cn/handle/321008/138948
Appears in Collections:中国科学院大连化学物理研究所_期刊论文

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作者单位: 1.Moscow MV Lomonosov State Univ, Fac Chem, Moscow 119899, Russia
2.Samara State Tech Univ, Samara, Russia
3.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian, Peoples R China

Recommended Citation:
Varushchenko, RM,Druzhinina, AI,Churkina, AY,et al. The low-temperature heat capacity and thermodynamic functions of propyl tert-butyl ethers[J]. RUSSIAN JOURNAL OF PHYSICAL CHEMISTRY,2001,75(8):1223-1231.
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