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题名: Laser ablation of Co/Ge mixtures: a new type of endohedral structure, a semiconductor cage trapping a metal atom
作者: Zhang, X;  Li, GL;  Gao, Z
刊名: RAPID COMMUNICATIONS IN MASS SPECTROMETRY
发表日期: 2001
卷: 15, 期:17, 页:1573-1576
收录类别: SCI
文章类型: Article
WOS标题词: Science & Technology ;  Physical Sciences ;  Technology
类目[WOS]: Chemistry, Analytical ;  Spectroscopy
研究领域[WOS]: Chemistry ;  Spectroscopy
英文摘要: In experiments on Co/Ge binary clusters by laser vaporization, a remarkably strong signal in the mass spectrum was presented, which was assigned to the cluster anion consisting of ten germanium atoms and one cobalt atom, [CoGe10](-). For this cluster anion we suggest an endohedral structure - a Ge-10 cage trapping a Co atom in its interior. Reactions between cobalt clusters and germanium clusters using a laser double ablation reactor also confirmed the endohedral structure. According to the electronic and geometrical shell closures, a bicapped tetragonal antiprism structure was predicted for this endohedral [CoGe10](-) cluster anion. Copyright (C) 2001 John Wiley & Sons, Ltd.
关键词[WOS]: SPHEROIDAL CARBON SHELLS ;  ELECTRONIC STATES ;  COMPLEXES ;  DIMETALLOFULLERENES ;  METALLOFULLERENE ;  LA-2-AT-C-80 ;  CLUSTERS ;  LA
语种: 英语
WOS记录号: WOS:000170833500012
Citation statistics: 
内容类型: 期刊论文
URI标识: http://cas-ir.dicp.ac.cn/handle/321008/138954
Appears in Collections:中国科学院大连化学物理研究所_期刊论文

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作者单位: 1.Chinese Acad Sci, Inst Chem, Ctr Mol Sci, State Key Lab Mol React Dynam, Beijing 100080, Peoples R China

Recommended Citation:
Zhang, X,Li, GL,Gao, Z. Laser ablation of Co/Ge mixtures: a new type of endohedral structure, a semiconductor cage trapping a metal atom[J]. RAPID COMMUNICATIONS IN MASS SPECTROMETRY,2001,15(17):1573-1576.
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