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题名: IR spectroscopic study on surface-mediated reductive carbonylation of hydrated SiO2-supported Ru(NO3)(3)
作者: Huang, L;  Xu, Y
关键词: silica ;  Ru(NO3)(3) ;  reductive carbonylation
刊名: CATALYSIS LETTERS
发表日期: 2001
卷: 71, 期:1-2, 页:27-30
收录类别: SCI
文章类型: Article
WOS标题词: Science & Technology ;  Physical Sciences
类目[WOS]: Chemistry, Physical
研究领域[WOS]: Chemistry
英文摘要: The surface-mediated reductive carbonylation of hydrated SiO2-supported Ru(NO3)(3) has been studied by IR spectroscopy. At 25 degreesC, hydrated Ru(NO3)(3)/SiO2 reacts with CO to give a mixture of Ru(CO)(2)(OSi)(2) and Ru(CO)(3)(OSi)(2). At 100 degreesC, hydrated Ru(NO3)3/SiO2 is converted to a mixture of Ru(CO)(2)(OSi)(2) and Ru(CO)(3)(OSi)(2) under 100 Torr of CO, and a mixture of Ru-3(CO)(12) and Ru(CO)(3)(OSi)(2) under 700 Torr of CO.
关键词[WOS]: ORGANOMETALLIC SYNTHESIS ;  COBALT CARBONYLS ;  SILICA ;  CATALYSTS ;  CLUSTERS ;  CO ;  HYDROFORMYLATION ;  <OS(CO)3CL2>2 ;  REACTIVITY ;  SIO2
语种: 英语
WOS记录号: WOS:000168379800005
Citation statistics: 
内容类型: 期刊论文
URI标识: http://cas-ir.dicp.ac.cn/handle/321008/138984
Appears in Collections:中国科学院大连化学物理研究所_期刊论文

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作者单位: 1.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Peoples R China

Recommended Citation:
Huang, L,Xu, Y. IR spectroscopic study on surface-mediated reductive carbonylation of hydrated SiO2-supported Ru(NO3)(3)[J]. CATALYSIS LETTERS,2001,71(1-2):27-30.
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