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题名: Studies on the carbonylation of carbon dioxide under single wavelength visible light irradiation
作者: Zhuang, JQ;  Yin, JM;  Gao, DB;  Zheng, XF;  Zhou, GY;  Zhou, NZ;  Wang, XS;  Guo, XW
关键词: single wavelength ;  visible light ;  carbon dioxide ;  carbonylation
刊名: CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE
发表日期: 2001
卷: 22, 期:1, 页:75-77
收录类别: SCI
文章类型: Article
WOS标题词: Science & Technology ;  Physical Sciences
类目[WOS]: Chemistry, Multidisciplinary
研究领域[WOS]: Chemistry
英文摘要: It is the first time to report the carbonylation of cyclohexene with carbon dioxide under ambient conditions irradiated at single wavelength visible light. The effects of catalysts, the additives and different wavelength have been investigated, which indicated that the metal complexes such as CoTPP and MnTPP acted as catalyst of the carbonylation as well as sensitizer under the irradiation of special wavelength visible light. Furthermore, when adding sodium proponiate to the solution, the catalysts such as PCFe would be activated and the formation of ester was promoted obviously. We also detected the quantum yield, of this reaction and found it can reach to 10(-2). As far as the quantum yield and taking good advantage of the energy from solar was concerned. HSO3PCCo was the better catalyst for the carbonylation.
语种: 英语
WOS记录号: WOS:000167569400020
Citation statistics: 
内容类型: 期刊论文
URI标识: http://cas-ir.dicp.ac.cn/handle/321008/139002
Appears in Collections:中国科学院大连化学物理研究所_期刊论文

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作者单位: 1.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Peoples R China
2.Dalian Univ, Dept Chem & Chem Engn, Dalian 116622, Peoples R China
3.Dalian Univ Technol, Educ Minist Open Lab Carbon Resource Utilizat, Dalian 116012, Peoples R China

Recommended Citation:
Zhuang, JQ,Yin, JM,Gao, DB,et al. Studies on the carbonylation of carbon dioxide under single wavelength visible light irradiation[J]. CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE,2001,22(1):75-77.
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