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Extremely rotationally excited OH from water (HOD) photodissociation through conical intersection
Harich, SA; Yang, YF; Yang, XM
刊名PHYSICAL REVIEW LETTERS
2001-12-17
DOI10.1103/PhysRevLett.87.253201
87期:25
收录类别SCI
文章类型Article
WOS标题词Science & Technology ; Physical Sciences
类目[WOS]Physics, Multidisciplinary
研究领域[WOS]Physics
关键词[WOS]DYNAMICS ; H2O ; DISSOCIATION ; NM
英文摘要Photodissociation of HOD from the (B) over tilde state has been studied using the Rydberg "tagging" time-of-flight technique. Experimental results indicate that extreme rotational excitation in the OH(X, v = 0) product (N up to 50 or so) is produced through the conical intersection dissociation pathway such that some of the OH product states lie above the O(P-3) + H dissociation limit, which are supported only through large centrifugal barriers. The population distribution for OH(X, v = 0) also shows an alternation with N, similar to that observed for H2O that is attributed to dynamical interference. The tunneling rates of these extremely rotationally excited OH molecules are also analyzed.
语种英语
WOS记录号WOS:000172866200023
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文献类型期刊论文
条目标识符http://cas-ir.dicp.ac.cn/handle/321008/139004
专题中国科学院大连化学物理研究所
作者单位1.Acad Sinica, Inst Atom & Mol Sci, Taipei, Taiwan
2.Natl Tsing Hua Univ, Dept Chem, Hsinchu, Taiwan
3.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian, Peoples R China
4.Univ Bristol, Sch Chem, Bristol BS8 1TS, Avon, England
5.Dalian Univ Technol, Dept Chem, Dalian, Peoples R China
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Harich, SA,Yang, YF,Yang, XM. Extremely rotationally excited OH from water (HOD) photodissociation through conical intersection[J]. PHYSICAL REVIEW LETTERS,2001,87(25).
APA Harich, SA,Yang, YF,&Yang, XM.(2001).Extremely rotationally excited OH from water (HOD) photodissociation through conical intersection.PHYSICAL REVIEW LETTERS,87(25).
MLA Harich, SA,et al."Extremely rotationally excited OH from water (HOD) photodissociation through conical intersection".PHYSICAL REVIEW LETTERS 87.25(2001).
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