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Extremely rotationally excited OH from water (HOD) photodissociation through conical intersection
Harich, SA; Yang, YF; Yang, XM
Source PublicationPHYSICAL REVIEW LETTERS
2001-12-17
DOI10.1103/PhysRevLett.87.253201
Volume87Issue:25
Indexed BySCI
SubtypeArticle
WOS HeadingsScience & Technology ; Physical Sciences
WOS SubjectPhysics, Multidisciplinary
WOS Research AreaPhysics
WOS KeywordDYNAMICS ; H2O ; DISSOCIATION ; NM
AbstractPhotodissociation of HOD from the (B) over tilde state has been studied using the Rydberg "tagging" time-of-flight technique. Experimental results indicate that extreme rotational excitation in the OH(X, v = 0) product (N up to 50 or so) is produced through the conical intersection dissociation pathway such that some of the OH product states lie above the O(P-3) + H dissociation limit, which are supported only through large centrifugal barriers. The population distribution for OH(X, v = 0) also shows an alternation with N, similar to that observed for H2O that is attributed to dynamical interference. The tunneling rates of these extremely rotationally excited OH molecules are also analyzed.
Language英语
WOS IDWOS:000172866200023
Citation statistics
Cited Times:29[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://cas-ir.dicp.ac.cn/handle/321008/139004
Collection中国科学院大连化学物理研究所
Affiliation1.Acad Sinica, Inst Atom & Mol Sci, Taipei, Taiwan
2.Natl Tsing Hua Univ, Dept Chem, Hsinchu, Taiwan
3.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian, Peoples R China
4.Univ Bristol, Sch Chem, Bristol BS8 1TS, Avon, England
5.Dalian Univ Technol, Dept Chem, Dalian, Peoples R China
Recommended Citation
GB/T 7714
Harich, SA,Yang, YF,Yang, XM. Extremely rotationally excited OH from water (HOD) photodissociation through conical intersection[J]. PHYSICAL REVIEW LETTERS,2001,87(25).
APA Harich, SA,Yang, YF,&Yang, XM.(2001).Extremely rotationally excited OH from water (HOD) photodissociation through conical intersection.PHYSICAL REVIEW LETTERS,87(25).
MLA Harich, SA,et al."Extremely rotationally excited OH from water (HOD) photodissociation through conical intersection".PHYSICAL REVIEW LETTERS 87.25(2001).
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