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题名: Inclusion properties of ball-shaped clathrate hosts and its application to preparing organic non-linear optical materials
作者: Guo, WS;  Guo, F;  Deng, M;  Ge, CH;  Liu, QT;  Tian, ZY;  Wang, SC;  Zheng, QT
关键词: inclusion compounds ;  spherical host molecule ;  phenol-type guest molecule ;  SHG effect
刊名: ACTA CHIMICA SINICA
发表日期: 2001
卷: 59, 期:2, 页:284-290
收录类别: SCI
文章类型: Article
WOS标题词: Science & Technology ;  Physical Sciences
类目[WOS]: Chemistry, Multidisciplinary
研究领域[WOS]: Chemistry
英文摘要: This paper introduces design idea of spherical clathrate hosts which uses cedrol (1), brucine(2), 1,4 - diazabicyclo[2.2.2] octane (3) endowed of ball - shaped rigid molecular backbone as host molecules and phenol - type molecules such as phenol (4), o - cresol (5), m - cresol (6), p - cresol (7), 4 chrolophenol (8), 4 - methoxyphenol (9), 4 - hydroxylbenzaldehyde (10), 4 - nitrophenol (11) and maleicanhydride (12) used as guest molecules. We have carried out inclusion experiment using these hosts with phenol- type compounds. The formation of inclusion compounds were confirmed by means of powder XRD, and the molar ratios of inclusion compounds were determined by H-1 NMR, (1) + (4) 1:1,(1) + (5) 1:1, (7) 1:2, (3)+(8) 1:2, (3)+(9) 1:2, (3) + (11) 1:2 as results. The single crystal structure of a few typical. inclusion compounds was determined by X- ray diffraction analysis and showed that the variation of architectural structure characteristic of inclusion compounds depends on the volume size of the host molecules from channel type as with (1) + (5) and (2) + (11) to intercalate as with (3) + (11). The SHG effect of the inclusion compound crystals was inspected by Nd: YAG laser and the results showed that a mass of prepared inclusion crystals exhibits non - linear optical property.
关键词[WOS]: RAY CRYSTAL-STRUCTURES ;  DESIGN
语种: 英语
WOS记录号: WOS:000167632500025
Citation statistics: 
内容类型: 期刊论文
URI标识: http://cas-ir.dicp.ac.cn/handle/321008/139013
Appears in Collections:中国科学院大连化学物理研究所_期刊论文

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作者单位: 1.Liaoning Univ, Inst Chem Sci & Engn, Shenyang 110036, Peoples R China
2.Dalian Inst Chem Phys, State Key Lab Mol React Dynam, Dalian 116023, Peoples R China
3.Chinese Acad Med Sci, Inst Mat Med, Beijing 100050, Peoples R China

Recommended Citation:
Guo, WS,Guo, F,Deng, M,et al. Inclusion properties of ball-shaped clathrate hosts and its application to preparing organic non-linear optical materials[J]. ACTA CHIMICA SINICA,2001,59(2):284-290.
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