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题名: Internal-state distribution and polarization in nascent NO X-2 Pi from the photodissociation of C6H5NO
作者: Li, YM;  Sun, JL;  Han, KL;  He, GZ
刊名: CHEMICAL PHYSICS LETTERS
发表日期: 2001-04-27
卷: 338, 期:4-6, 页:297-302
收录类别: SCI
文章类型: Article
WOS标题词: Science & Technology ;  Physical Sciences
类目[WOS]: Chemistry, Physical ;  Physics, Atomic, Molecular & Chemical
研究领域[WOS]: Chemistry ;  Physics
英文摘要: The 266 nm photodissociation of gaseous C6H5NO has been studied by monitoring the nascent NO (X(2)Pi upsilon " = 0-3) product using the single-photon laser-induced fluorescence technique. The rotational-state distributions of the nascent NO photofragment have been measured and can be characterized by Bolzmann temperatures. The vibrational-state and Lambda -doublet populations were also determined. Energy disposal into the internal degrees of freedom of NO (X(2)Pi) photofragment is about 18% of the total available energy. Some planarity in the fragmentation process was observed. (C) 2001 Published by Elsevier Science B.V.
关键词[WOS]: ENERGY-DISTRIBUTION ;  PRODUCT STATE ;  SUB-DOPPLER ;  DYNAMICS ;  NM ;  PHOTOFRAGMENTATION ;  FRAGMENT ;  HONO ;  NITROSOBENZENE ;  SPECTROSCOPY
语种: 英语
WOS记录号: WOS:000168591800013
Citation statistics: 
内容类型: 期刊论文
URI标识: http://cas-ir.dicp.ac.cn/handle/321008/139032
Appears in Collections:中国科学院大连化学物理研究所_期刊论文

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作者单位: 1.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Mol React Dynam, Dalian 116023, Peoples R China

Recommended Citation:
Li, YM,Sun, JL,Han, KL,et al. Internal-state distribution and polarization in nascent NO X-2 Pi from the photodissociation of C6H5NO[J]. CHEMICAL PHYSICS LETTERS,2001,338(4-6):297-302.
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