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题名: Formation and photodissociation of copper-selenium clusters
作者: Chen, YQ;  Xing, XP;  Gao, Z;  Zhu, QH
关键词: Cu/Se cluster ;  laser ablation ;  tandem time-flight mass spectrum ;  UV photodissociation ;  density function theory
刊名: CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE
发表日期: 2002-11-01
卷: 23, 期:11, 页:2147-2150
收录类别: SCI
文章类型: Article
WOS标题词: Science & Technology ;  Physical Sciences
类目[WOS]: Chemistry, Multidisciplinary
研究领域[WOS]: Chemistry
英文摘要: The formation and photodissociation of Cu/Se binary clusters were studied on the laser ablation tandem time-of-flight mass spectrometer. It was found that the cations [Cu(Cu2Se)(n)](+) and [(Cu2Se)(n)](+) the anions [CuSe(Cu2Se)](-),, [(Cu2Se)(n)Se](-) were the main products. In the photodissociation experiment of CunSem+, [Cu(Cu2Se)(n)](+) and [(Cu2Se)(n)](+) were the main products. The structures and photodissociation channels of Cu3Se+, Cu5Se2+ were studied by using a kind of "DFT" method, in which the LANL2-DZ basis was used.
关键词[WOS]: IONS
语种: 英语
WOS记录号: WOS:000179416200033
Citation statistics: 
内容类型: 期刊论文
URI标识: http://cas-ir.dicp.ac.cn/handle/321008/139056
Appears in Collections:中国科学院大连化学物理研究所_期刊论文

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作者单位: 1.Chinese Acad Sci, Inst Chem, Ctr Mol Sci, State Key Lab Mol React Dynam, Beijing 100080, Peoples R China

Recommended Citation:
Chen, YQ,Xing, XP,Gao, Z,et al. Formation and photodissociation of copper-selenium clusters[J]. CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE,2002,23(11):2147-2150.
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