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题名: Dimerization of propylene catalyzed by neutral salicylaidiminato Ni(II) complex containing phosphine ligand
作者: Wu, SZ;  Lu, SW
关键词: salicylaldimine ligand ;  nickel(II)-phosphine complex ;  propylene ;  dimerization ;  methylpentene ;  hexene ;  dimethylbutene ;  organoatuminium cocatalyst
刊名: CHINESE JOURNAL OF CATALYSIS
发表日期: 2002-03-01
卷: 23, 期:2, 页:133-136
收录类别: SCI
文章类型: Article
WOS标题词: Science & Technology ;  Physical Sciences ;  Technology
类目[WOS]: Chemistry, Applied ;  Chemistry, Physical ;  Engineering, Chemical
研究领域[WOS]: Chemistry ;  Engineering
英文摘要: The performance of a series of neutral salicylaldiminato Ni complexes containing phosphine ligand was tested in dimerization of propylene activated by organoaluminium cocatalyst. Moreover, the effects of Al/Ni ratio, propylene pressure, alkyl aluminum and different substituted groups in salicylaldimine ligand on the reaction were investigated. The results indicated that the catalytic activity of this system for dimerization of propylene is high and the selectivity is high too. 4-Methylpentenes are the main product of the dimers, the other dimers are composed of some 2-methylpentenes and hexenes besides minor 2, 3-dimethylbutenes.
关键词[WOS]: ZIEGLER-TYPE CATALYSTS ;  2,3-DIMETHYLBUTENES ;  OLIGOMERIZATION
语种: 英语
WOS记录号: WOS:000175026000012
Citation statistics: 
内容类型: 期刊论文
URI标识: http://cas-ir.dicp.ac.cn/handle/321008/139099
Appears in Collections:中国科学院大连化学物理研究所_期刊论文

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作者单位: 1.Acad Sinica, Dalian Inst Chem Phys, Natl Engn Res Ctr Catalysis, Dalian Chem Phy Chem Co Ltd, Dalian 116011, Liaoning, Peoples R China

Recommended Citation:
Wu, SZ,Lu, SW. Dimerization of propylene catalyzed by neutral salicylaidiminato Ni(II) complex containing phosphine ligand[J]. CHINESE JOURNAL OF CATALYSIS,2002,23(2):133-136.
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