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题名: Catalytic performance of perovskite oxide catalysts for partial oxidation of methane to syngas
作者: Chu, WL;  Yang, WS;  Lin, LW
关键词: Ba0.5Sr0.5Co0.8Fe0.2O3-delta ;  Ba0.5Sr0.5Co0.8Ti0.2O3-delta ;  partial oxidation of methane ;  CH4 pre-treatment
刊名: CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE
发表日期: 2002-09-01
卷: 23, 期:9, 页:1787-1789
收录类别: SCI
文章类型: Letter
WOS标题词: Science & Technology ;  Physical Sciences
类目[WOS]: Chemistry, Multidisciplinary
研究领域[WOS]: Chemistry
英文摘要: Ba0.5Sr0.5Co0.8Fe0.2O3-delta and Ba0.5Sr0.5Co0.8Ti0.2O3-delta oxides were synthesized by a combined EDTA-citrate complexing method. The catalytic behavior of these two oxides with the perovskite structure was studied during the reaction of methane oxidation. The pre-treatment with methane has different effect on the catalytic activities of both the oxides. The methane pre-treatment has not resulted in the change of the catalytic activity of BSCFO owing to its excellent reversibility of the perovskite structure resulting from the excellent synergistic interaction between Co and Fe in the oxide. However, the substitution with Ti on Fe-site in the lattice makes the methane pre-treatment have an obvious influence on the activity of the formed BSCTO oxide.
关键词[WOS]: SYNTHESIS GAS ;  SELECTIVE OXIDATION ;  CO
语种: 英语
WOS记录号: WOS:000178056800040
Citation statistics: 
内容类型: 期刊论文
URI标识: http://cas-ir.dicp.ac.cn/handle/321008/139161
Appears in Collections:中国科学院大连化学物理研究所_期刊论文

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作者单位: 1.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Peoples R China

Recommended Citation:
Chu, WL,Yang, WS,Lin, LW. Catalytic performance of perovskite oxide catalysts for partial oxidation of methane to syngas[J]. CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE,2002,23(9):1787-1789.
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