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Clay-intercalated metal complex catalysts and their molecular recognition catalysis
Tao, LX; Zou, DX
关键词Catalysts Clay Metal Complexes Heterogenization Molecular Recognition Regioselectivity
刊名PROGRESS IN CHEMISTRY
2002-05-01
14期:3页:200-206
收录类别SCI
文章类型Article
WOS标题词Science & Technology ; Physical Sciences
类目[WOS]Chemistry, Multidisciplinary
研究领域[WOS]Chemistry
关键词[WOS]TITANIUM-PILLARED MONTMORILLONITE ; SHAPE SELECTIVE HYDROGENATION ; ASYMMETRIC HYDROGENATION ; SMECTITE CLAY ; OXIDATION CATALYSTS ; IMMOBILIZATION ; CARBONYLATION ; HECTORITE ; OLEFINS ; HYDROESTERIFICATION
英文摘要The expandable layers of clay provide useful two dimensional hosts which facilitate introduction of catalytical active metal complexes by cation exchange and ligand exchange methods. Intercalation of metal complexes into the interlamellar space of clay is an excellent method for homogeneous catalyst heterogenization. Clay-intercalated metal complex catalysts display molecular-recognizing catalysis, such as shape selectivity, steroselectivity, regioselectivity. The application of these heterogenized catalysts in the asymmetric hydrogenation, regioselective hydrogenation, regioselective carbonylation and steroselective arylation is described in this review. Clay-intercalated metal complex catalysts exhibit sufficiently high activity and selectivity to make them competitive to the homogeneous catalysts.
语种英语
WOS记录号WOS:000177413200006
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被引频次:5[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://cas-ir.dicp.ac.cn/handle/321008/139163
专题中国科学院大连化学物理研究所
作者单位Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Peoples R China
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GB/T 7714
Tao, LX,Zou, DX. Clay-intercalated metal complex catalysts and their molecular recognition catalysis[J]. PROGRESS IN CHEMISTRY,2002,14(3):200-206.
APA Tao, LX,&Zou, DX.(2002).Clay-intercalated metal complex catalysts and their molecular recognition catalysis.PROGRESS IN CHEMISTRY,14(3),200-206.
MLA Tao, LX,et al."Clay-intercalated metal complex catalysts and their molecular recognition catalysis".PROGRESS IN CHEMISTRY 14.3(2002):200-206.
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