TPO (temperature-programmed oxidation), TPSR (temperature-programmed surface reaction), and TPH (temperature-programmed hydrogenation) techniques are used to investigate carbonaceous deposition on Mo/HMCM-22 catalysts for methane aromatization. Different carbonaceous species and their amounts are distinguished. There are at least three kinds of cokes: carbidic carbon in molybdenum carbide, molybdenum-associated coke, and aromatic-type cokes on acid sites. It is suggested that the aromatic-type cokes on Bronsted acid sites are responsible for catalyst deactivation. Catalytic activity can be restored after temperature-programmed hydrogenation. (C) 2002 Elsevier Science (USA).
1.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Peoples R China
Recommended Citation:
Ma, D,Wang, DZ,Su, LL,et al. Carbonaceous deposition on Mo/HMCM-22 catalysts for methane aromatization: A TP technique investigation[J]. JOURNAL OF CATALYSIS,2002,208(2):260-269.
