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题名: CuO-NiO/SO2 catalyzed oxidation of 1-methoxy-2-propanol to methoxyacetone
作者: Wang, JW;  Cao, GY;  Hu, XQ
关键词: copper oxide ;  nickel oxide ;  silica ;  synergic catalytic effect ;  methoxypropanol ;  methoxyacetone
刊名: CHINESE JOURNAL OF CATALYSIS
发表日期: 2002-07-01
卷: 23, 期:4, 页:349-351
收录类别: SCI
文章类型: Article
WOS标题词: Science & Technology ;  Physical Sciences ;  Technology
类目[WOS]: Chemistry, Applied ;  Chemistry, Physical ;  Engineering, Chemical
研究领域[WOS]: Chemistry ;  Engineering
英文摘要: The oxidation of 1-methoxy-2-propanol to methoxyacetone catalyzed by 15%CuO-19.5%NiO/SiO2 catalyst was studied, using air as oxygen source. The results showed that NiO and CuO had a great synergic catalytic effect, and the quantity of supported active components played an important role in the catalytic reaction. TPR and XRD results showed that the addition of NiO significantly improved the dispersion of CuO over SiO2 and reduced the reduction temperature of the oxides. A 63% yield of methoxyacetone with a 74.3% conversion of 1-methoxy-2-propanol was obtained under an optimized condition.
关键词[WOS]: LIQUID-PHASE OXIDATION ;  PALLADIUM CATALYSTS ;  AIR ;  DEACTIVATION ;  LEAD
语种: 英语
WOS记录号: WOS:000177387000016
Citation statistics: 
内容类型: 期刊论文
URI标识: http://cas-ir.dicp.ac.cn/handle/321008/139201
Appears in Collections:中国科学院大连化学物理研究所_期刊论文

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作者单位: 1.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Liaoning, Peoples R China

Recommended Citation:
Wang, JW,Cao, GY,Hu, XQ. CuO-NiO/SO2 catalyzed oxidation of 1-methoxy-2-propanol to methoxyacetone[J]. CHINESE JOURNAL OF CATALYSIS,2002,23(4):349-351.
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