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题名: A highly enantioselective phase-transfer catalyzed epoxidation of enones with a mild oxidant, trichloroisocyanuric acid
作者: Ye, JX;  Wang, YC;  Liu, RH;  Zhang, GF;  Zhang, Q;  Chen, JP;  Liang, XM
刊名: CHEMICAL COMMUNICATIONS
发表日期: 2003-11-07
DOI: 10.1039/b308042k
期: 21, 页:2714-2715
收录类别: SCI ;  CCR
文章类型: Article
WOS标题词: Science & Technology ;  Physical Sciences
类目[WOS]: Chemistry, Multidisciplinary
研究领域[WOS]: Chemistry
英文摘要: The enantioselective epoxidation can be carried out using trichloroisocyanuric acid (TCCA) as oxidant in the presence of chiral quaternary ammonium salt as a phase-transfer catalyst; treatment of chalcone derivatives with TCCA under mild conditions afforded the corresponding epoxy ketones in good yields with moderate to excellent enantioselectivities of up to 96%.
关键词[WOS]: TRANSFER MEDIATED EPOXIDATION ;  ASYMMETRIC EPOXIDATION ;  ALPHA,BETA-UNSATURATED KETONES ;  CINCHONA ALKALOIDS ;  DIRECT CONVERSION ;  ALCOHOLS ;  OXIDATION
语种: 英语
WOS记录号: WOS:000186492000034
Citation statistics: 
内容类型: 期刊论文
URI标识: http://cas-ir.dicp.ac.cn/handle/321008/139255
Appears in Collections:中国科学院大连化学物理研究所_期刊论文

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作者单位: 1.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116011, Peoples R China

Recommended Citation:
Ye, JX,Wang, YC,Liu, RH,et al. A highly enantioselective phase-transfer catalyzed epoxidation of enones with a mild oxidant, trichloroisocyanuric acid[J]. CHEMICAL COMMUNICATIONS,2003(21):2714-2715.
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