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A highly enantioselective phase-transfer catalyzed epoxidation of enones with a mild oxidant, trichloroisocyanuric acid
Ye, JX; Wang, YC; Liu, RH; Zhang, GF; Zhang, Q; Chen, JP; Liang, XM
Source PublicationCHEMICAL COMMUNICATIONS
2003-11-07
DOI10.1039/b308042k
Issue21Pages:2714-2715
Indexed BySCI ; CCR
SubtypeArticle
WOS HeadingsScience & Technology ; Physical Sciences
WOS SubjectChemistry, Multidisciplinary
WOS Research AreaChemistry
WOS KeywordTRANSFER MEDIATED EPOXIDATION ; ASYMMETRIC EPOXIDATION ; ALPHA,BETA-UNSATURATED KETONES ; CINCHONA ALKALOIDS ; DIRECT CONVERSION ; ALCOHOLS ; OXIDATION
AbstractThe enantioselective epoxidation can be carried out using trichloroisocyanuric acid (TCCA) as oxidant in the presence of chiral quaternary ammonium salt as a phase-transfer catalyst; treatment of chalcone derivatives with TCCA under mild conditions afforded the corresponding epoxy ketones in good yields with moderate to excellent enantioselectivities of up to 96%.
Language英语
WOS IDWOS:000186492000034
Citation statistics
Cited Times:58[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://cas-ir.dicp.ac.cn/handle/321008/139255
Collection中国科学院大连化学物理研究所
AffiliationChinese Acad Sci, Dalian Inst Chem Phys, Dalian 116011, Peoples R China
Recommended Citation
GB/T 7714
Ye, JX,Wang, YC,Liu, RH,et al. A highly enantioselective phase-transfer catalyzed epoxidation of enones with a mild oxidant, trichloroisocyanuric acid[J]. CHEMICAL COMMUNICATIONS,2003(21):2714-2715.
APA Ye, JX.,Wang, YC.,Liu, RH.,Zhang, GF.,Zhang, Q.,...&Liang, XM.(2003).A highly enantioselective phase-transfer catalyzed epoxidation of enones with a mild oxidant, trichloroisocyanuric acid.CHEMICAL COMMUNICATIONS(21),2714-2715.
MLA Ye, JX,et al."A highly enantioselective phase-transfer catalyzed epoxidation of enones with a mild oxidant, trichloroisocyanuric acid".CHEMICAL COMMUNICATIONS .21(2003):2714-2715.
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