中国科学院大连化学物理研究所机构知识库
Advanced  
DICP OpenIR  > 中国科学院大连化学物理研究所  > 期刊论文
题名: The anion photoelectron spectrometer used in studying binary metal anion cluster
作者: Xing, XP;  Liu, HT;  Sun, ST;  Cao, YL;  Tang, ZC
关键词: photoelectron spectrometer ;  laser ;  cluster
刊名: CHINESE JOURNAL OF CHEMICAL PHYSICS
发表日期: 2004-06-01
卷: 17, 期:3, 页:321-325
收录类别: SCI
文章类型: Article
WOS标题词: Science & Technology ;  Physical Sciences
类目[WOS]: Physics, Atomic, Molecular & Chemical
研究领域[WOS]: Physics
英文摘要: A home-made magnetic-bottle time-of-flight anion photoelectron spectrometer (PES) for the investigation of binary metal cluster geometry and electron structure is described. The photoelectron spectrometer is installed near the first space focus of home-made reflectron time of flight mass spectrometer (RTOFMS), coupled with laser ablation, pulse supersonic molecular carrier gas cluster source. The magnetic-bottle photoelectron spectrometer's resolution is about 0.1 eV for 1 eV photoelectrons. The adiabatic electron affinity energies of neutral clusters and some features relative to their excited states can be obtained from the spectra, i.e., from the anion's spectra, not only the features of the anion but also the neutral clusters' features can be investigated. The detailed design, construction, and operation of the new apparatus are presented. And studied PbM- (M = Cu, Ag, Au) binary metal cluster anions, the results give clear diagram about their structures and the bond interactions. The adiabatic electron affinity energies obtained by the photoelectron spectrometer agree well with the calculated results using relativistic density functional theory(DFT) method. It show that this anion photoelectron spectrometer can be well used in studying binary metal cluster anions in the experiment condition.
关键词[WOS]: PLANAR CARBON ;  MOLECULES ;  SPECTROSCOPY ;  C-60
语种: 英语
WOS记录号: WOS:000222521100016
Citation statistics: 
内容类型: 期刊论文
URI标识: http://cas-ir.dicp.ac.cn/handle/321008/139301
Appears in Collections:中国科学院大连化学物理研究所_期刊论文

Files in This Item:

There are no files associated with this item.


作者单位: 1.Chinese Acad Sci, Inst Chem, Ctr Mol Sci, State Key Lab Mol React Dynam, Beijing 100080, Peoples R China

Recommended Citation:
Xing, XP,Liu, HT,Sun, ST,et al. The anion photoelectron spectrometer used in studying binary metal anion cluster[J]. CHINESE JOURNAL OF CHEMICAL PHYSICS,2004,17(3):321-325.
Service
 Recommend this item
 Sava as my favorate item
 Show this item's statistics
 Export Endnote File
Google Scholar
 Similar articles in Google Scholar
 [Xing, XP]'s Articles
 [Liu, HT]'s Articles
 [Sun, ST]'s Articles
CSDL cross search
 Similar articles in CSDL Cross Search
 [Xing, XP]‘s Articles
 [Liu, HT]‘s Articles
 [Sun, ST]‘s Articles
Related Copyright Policies
Null
Social Bookmarking
  Add to CiteULike  Add to Connotea  Add to Del.icio.us  Add to Digg  Add to Reddit 
所有评论 (0)
暂无评论
 
评注功能仅针对注册用户开放,请您登录
您对该条目有什么异议,请填写以下表单,管理员会尽快联系您。
内 容:
Email:  *
单位:
验证码:   刷新
您在IR的使用过程中有什么好的想法或者建议可以反馈给我们。
标 题:
 *
内 容:
Email:  *
验证码:   刷新

Items in IR are protected by copyright, with all rights reserved, unless otherwise indicated.

 

 

Valid XHTML 1.0!
Powered by CSpace