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The anion photoelectron spectrometer used in studying binary metal anion cluster
Xing, XP; Liu, HT; Sun, ST; Cao, YL; Tang, ZC
关键词Photoelectron Spectrometer Laser Cluster
刊名CHINESE JOURNAL OF CHEMICAL PHYSICS
2004-06-01
17期:3页:321-325
收录类别SCI
文章类型Article
WOS标题词Science & Technology ; Physical Sciences
类目[WOS]Physics, Atomic, Molecular & Chemical
研究领域[WOS]Physics
关键词[WOS]PLANAR CARBON ; MOLECULES ; SPECTROSCOPY ; C-60
英文摘要A home-made magnetic-bottle time-of-flight anion photoelectron spectrometer (PES) for the investigation of binary metal cluster geometry and electron structure is described. The photoelectron spectrometer is installed near the first space focus of home-made reflectron time of flight mass spectrometer (RTOFMS), coupled with laser ablation, pulse supersonic molecular carrier gas cluster source. The magnetic-bottle photoelectron spectrometer's resolution is about 0.1 eV for 1 eV photoelectrons. The adiabatic electron affinity energies of neutral clusters and some features relative to their excited states can be obtained from the spectra, i.e., from the anion's spectra, not only the features of the anion but also the neutral clusters' features can be investigated. The detailed design, construction, and operation of the new apparatus are presented. And studied PbM- (M = Cu, Ag, Au) binary metal cluster anions, the results give clear diagram about their structures and the bond interactions. The adiabatic electron affinity energies obtained by the photoelectron spectrometer agree well with the calculated results using relativistic density functional theory(DFT) method. It show that this anion photoelectron spectrometer can be well used in studying binary metal cluster anions in the experiment condition.
语种英语
WOS记录号WOS:000222521100016
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被引频次:11[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://cas-ir.dicp.ac.cn/handle/321008/139301
专题中国科学院大连化学物理研究所
作者单位Chinese Acad Sci, Inst Chem, Ctr Mol Sci, State Key Lab Mol React Dynam, Beijing 100080, Peoples R China
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Xing, XP,Liu, HT,Sun, ST,et al. The anion photoelectron spectrometer used in studying binary metal anion cluster[J]. CHINESE JOURNAL OF CHEMICAL PHYSICS,2004,17(3):321-325.
APA Xing, XP,Liu, HT,Sun, ST,Cao, YL,&Tang, ZC.(2004).The anion photoelectron spectrometer used in studying binary metal anion cluster.CHINESE JOURNAL OF CHEMICAL PHYSICS,17(3),321-325.
MLA Xing, XP,et al."The anion photoelectron spectrometer used in studying binary metal anion cluster".CHINESE JOURNAL OF CHEMICAL PHYSICS 17.3(2004):321-325.
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