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题名: (Z)-1-[2-(tribenzylstannyl)vinyl]-1-cyclooctanol: Synthesis, characterization, halodebenzylation, and crystal structure
作者: Ren, YJ;  Jun, H;  Yu, LH;  Li, MH;  Yang, XF;  Wan, BS;  Chen, HL
关键词: halodebenzylation ;  crystal sturcutre ;  (Z)-1-[2-(tribenzylstannyl)vinyl]-1-cyclooctanol
刊名: SYNTHESIS AND REACTIVITY IN INORGANIC AND METAL-ORGANIC CHEMISTRY
发表日期: 2004-03-01
卷: 34, 期:3, 页:565-572
收录类别: SCI ;  IC
文章类型: Article
WOS标题词: Science & Technology ;  Physical Sciences
类目[WOS]: Chemistry, Inorganic & Nuclear
研究领域[WOS]: Chemistry
英文摘要: The synthesis and properties of (Z)-1-[2-(tribenzyistannyl)vinyl]-1-cyclooctanol (1) are described. Compound (1) crystallizes from alcohol in the monoclinic space group P2(1)/c with unit-cell dimensions a = 9.348(1) Angstrom, b = 26.143(l) Angstrom, c = 10.705(l) Angstrom, beta = 95.09(1)degrees, V = 2605.9(1) Angstrom(3), Z = 4, D-c = 1.390 g cm(-3), mu = 10 cm(-1), final R = 0.033 for 3165 observed reflection (\F\(2) > 8sigma\F\(2)). The x-ray diffraction analysis of this compound shows intramolecular coordination of oxygen to the tin atom giving rise to a five-membered ring in which the metal exhibits a distorted trigonal bipyramidal geometry. Compound (1) by halodebenzylation by Br-2 or ICI forms the corresponding (Z)-1-[2-(dibenzylhalostannyl)vinyl]-1-cyclooctanol or (Z)-1-[2-(benzyldi-halostannyl)vinyl]-1-cyclooctanol, respectively. All compounds were characterized by elemental analyses, IR, H-1 NMR.
语种: 英语
WOS记录号: WOS:000220528100012
Citation statistics: 
内容类型: 期刊论文
URI标识: http://cas-ir.dicp.ac.cn/handle/321008/139303
Appears in Collections:中国科学院大连化学物理研究所_期刊论文

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作者单位: 1.Dalian Univ Technol, Dept Chem, Dalian 116024, Peoples R China
2.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian, Peoples R China
3.Jilin Univ, Changchun 130023, Peoples R China

Recommended Citation:
Ren, YJ,Jun, H,Yu, LH,et al. (Z)-1-[2-(tribenzylstannyl)vinyl]-1-cyclooctanol: Synthesis, characterization, halodebenzylation, and crystal structure[J]. SYNTHESIS AND REACTIVITY IN INORGANIC AND METAL-ORGANIC CHEMISTRY,2004,34(3):565-572.
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