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(Z)-1-[2-(tribenzylstannyl)vinyl]-1-cyclooctanol: Synthesis, characterization, halodebenzylation, and crystal structure
Ren, YJ; Jun, H; Yu, LH; Li, MH; Yang, XF; Wan, BS; Chen, HL
关键词Halodebenzylation Crystal Sturcutre (z)-1-[2-(Tribenzylstannyl)Vinyl]-1-cyclooctanol
刊名SYNTHESIS AND REACTIVITY IN INORGANIC AND METAL-ORGANIC CHEMISTRY
2004-03-01
34期:3页:565-572
收录类别SCI ; IC
文章类型Article
WOS标题词Science & Technology ; Physical Sciences
类目[WOS]Chemistry, Inorganic & Nuclear
研究领域[WOS]Chemistry
英文摘要The synthesis and properties of (Z)-1-[2-(tribenzyistannyl)vinyl]-1-cyclooctanol (1) are described. Compound (1) crystallizes from alcohol in the monoclinic space group P2(1)/c with unit-cell dimensions a = 9.348(1) Angstrom, b = 26.143(l) Angstrom, c = 10.705(l) Angstrom, beta = 95.09(1)degrees, V = 2605.9(1) Angstrom(3), Z = 4, D-c = 1.390 g cm(-3), mu = 10 cm(-1), final R = 0.033 for 3165 observed reflection (\F\(2) > 8sigma\F\(2)). The x-ray diffraction analysis of this compound shows intramolecular coordination of oxygen to the tin atom giving rise to a five-membered ring in which the metal exhibits a distorted trigonal bipyramidal geometry. Compound (1) by halodebenzylation by Br-2 or ICI forms the corresponding (Z)-1-[2-(dibenzylhalostannyl)vinyl]-1-cyclooctanol or (Z)-1-[2-(benzyldi-halostannyl)vinyl]-1-cyclooctanol, respectively. All compounds were characterized by elemental analyses, IR, H-1 NMR.
语种英语
WOS记录号WOS:000220528100012
引用统计
被引频次:1[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://cas-ir.dicp.ac.cn/handle/321008/139303
专题中国科学院大连化学物理研究所
作者单位1.Dalian Univ Technol, Dept Chem, Dalian 116024, Peoples R China
2.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian, Peoples R China
3.Jilin Univ, Changchun 130023, Peoples R China
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GB/T 7714
Ren, YJ,Jun, H,Yu, LH,et al. (Z)-1-[2-(tribenzylstannyl)vinyl]-1-cyclooctanol: Synthesis, characterization, halodebenzylation, and crystal structure[J]. SYNTHESIS AND REACTIVITY IN INORGANIC AND METAL-ORGANIC CHEMISTRY,2004,34(3):565-572.
APA Ren, YJ.,Jun, H.,Yu, LH.,Li, MH.,Yang, XF.,...&Chen, HL.(2004).(Z)-1-[2-(tribenzylstannyl)vinyl]-1-cyclooctanol: Synthesis, characterization, halodebenzylation, and crystal structure.SYNTHESIS AND REACTIVITY IN INORGANIC AND METAL-ORGANIC CHEMISTRY,34(3),565-572.
MLA Ren, YJ,et al."(Z)-1-[2-(tribenzylstannyl)vinyl]-1-cyclooctanol: Synthesis, characterization, halodebenzylation, and crystal structure".SYNTHESIS AND REACTIVITY IN INORGANIC AND METAL-ORGANIC CHEMISTRY 34.3(2004):565-572.
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