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题名: Quantum interference in collision-induced energy transfer for CO (A(1)Pi, v=0/e(3)Sigma(-),v=1)-HCl (X-1 Sigma) system studied by OODR-MPI spectroscopy
作者: Liu, J;  Sun, MT;  Jiang, B;  Sha, GH
刊名: CHEMICAL PHYSICS LETTERS
发表日期: 2004-04-21
DOI: 10.1016/j.cplett.2004.03.003
卷: 388, 期:4-6, 页:306-311
收录类别: SCI
文章类型: Article
WOS标题词: Science & Technology ;  Physical Sciences
类目[WOS]: Chemistry, Physical ;  Physics, Atomic, Molecular & Chemical
研究领域[WOS]: Chemistry ;  Physics
英文摘要: Quantum interference effect (QIE) in rotational energy transfer within CO (A(1)Pi, v = 0/e(3)Sigma(-), v = 1) mixed states in collision with HCl are observed with the interference phase angle theta(ST) of 101degrees and 110degrees for DeltaJ = +/-1 transition, respectively, from the initial J = 12 and 13 states. In comparison with the previous similar experiments with He et al. as collision partner, which all give a theta(ST) < 90&DEG;, the interference for a same CO transition in collision with HCl changes from constructive to destructive or the reverse since COS 0(ST) becomes negative. The bigger OST May be explained by the long-range dipole-dipole interaction of proportional to R-3. The physical significance Of θ(ST) is discussed in some details. © 2004 Elsevier B.V. All rights reserved.
关键词[WOS]: TRIPLET MIXED STATES ;  MULTIPHOTON IONIZATION ;  BEHAVIOR ;  PATHWAYS ;  MOLECULE
语种: 英语
WOS记录号: WOS:000220935600014
Citation statistics: 
内容类型: 期刊论文
URI标识: http://cas-ir.dicp.ac.cn/handle/321008/139318
Appears in Collections:中国科学院大连化学物理研究所_期刊论文

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作者单位: 1.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Mol React Dynam, Dalian 116023, Peoples R China

Recommended Citation:
Liu, J,Sun, MT,Jiang, B,et al. Quantum interference in collision-induced energy transfer for CO (A(1)Pi, v=0/e(3)Sigma(-),v=1)-HCl (X-1 Sigma) system studied by OODR-MPI spectroscopy[J]. CHEMICAL PHYSICS LETTERS,2004,388(4-6):306-311.
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