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题名: Crossed molecular beam studies of the fluorine atom reaction with trans-1,3-butadiene
作者: Gu, QL;  Wang, XY;  Shen, GL;  Yang, CX;  Ran, Q;  Yang, XM
关键词: crossed molecular beam ;  trans-1,3-butadiene ;  fluorine atom
刊名: CHINESE JOURNAL OF CHEMICAL PHYSICS
发表日期: 2004-02-01
卷: 17, 期:1, 页:15-20
收录类别: SCI
文章类型: Article
WOS标题词: Science & Technology ;  Physical Sciences
类目[WOS]: Physics, Atomic, Molecular & Chemical
研究领域[WOS]: Physics
英文摘要: The fluorine atom reaction with trans-1,3-butadiene has been investigated by using the crossed molecular beam method. Signals at mass 72, 46 and 33 have been observed. A single reaction channel C4H5F + H is observed for this reaction channel. Product angular distributions and velocity distributions are determined. The experimental results indicate that the channel mainly proceeds via a long-lived complex at a collisional energy of 23.8 kJ/mol. The collision complex is likely formed with the F atom attacking the delocalized electrons in the direction perpendicular to the molecular plane of trans-1,3-butadiene molecule.
关键词[WOS]: SCATTERING
语种: 英语
WOS记录号: WOS:000220151200005
Citation statistics: 
内容类型: 期刊论文
URI标识: http://cas-ir.dicp.ac.cn/handle/321008/139331
Appears in Collections:中国科学院大连化学物理研究所_期刊论文

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作者单位: 1.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Mol React Dynam, Dalian 116023, Peoples R China
2.Acad Sinica, Inst Atom & Mol Sci, Taipei, Taiwan
3.Natl Taiwan Univ, Dept Chem, Taipei 10764, Taiwan

Recommended Citation:
Gu, QL,Wang, XY,Shen, GL,et al. Crossed molecular beam studies of the fluorine atom reaction with trans-1,3-butadiene[J]. CHINESE JOURNAL OF CHEMICAL PHYSICS,2004,17(1):15-20.
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