DICP OpenIR
A new product channel in the energy transfer of CO (a, v ') plus NO(X)
Zhang, L; Zhang, M; Li, XC; Wang, XY; Shen, GL
KeywordSingle Collision Energy Transfer Electron Exchange Mechanism
Source PublicationCHINESE JOURNAL OF CHEMICAL PHYSICS
2004-02-01
Volume17Issue:1Pages:10-14
Indexed BySCI
SubtypeArticle
WOS HeadingsScience & Technology ; Physical Sciences
WOS SubjectPhysics, Atomic, Molecular & Chemical
WOS Research AreaPhysics
WOS KeywordEXCITATION ; BEAMS ; NO
AbstractUnder single-collision conditions, a beam of metastable molecules CO ( a, v) generated by DC discharge was allowed to collide with a beam of NO(X) at a fixed angle of 90degrees. The collision-induced emission from the interaction region was collected at right angles to the beam plane by a lens set and dispersed by a I in monochromator where a cooled photomultiplier tube was mounted on the exit slit. The signal from the PMT was transmitted via a discriminator, a photon counter and a boxcar integrator into a computer for storing and processing. Two broadband emissions were observed around the wavelengths of 780 and 860 nm, which can be assigned to NO(b-a) Ogawa bands Deltanu = + 4 and + 3 sequences, respectively, and referred to the spectroscopic data given by Huber. At the collision energy of 0.05 eV in the present experimental conditions, the electronic energy of CO ( a, V = 0) (6.01 eV) was not enough to excite NO ( X) to NO (b, nu' = 4,5) (DeltaE > 6.11 eV). So, what was in act in the energy transfer was the vibrational excitation of CO ( a, nu' > 0), and the higher the vibrational excitation of CO ( a, V) was, the stronger the emission intensity of NO( b-a) could be obtained. It is thought that electron exchange between CO ( a) and NO ( X) may be operative through the formation of a complex OCNO. The newly discovered formation of NO ( b) channel could be well explained considering the energy conservation, spin conservation and electron exchange mechanism.
Language英语
WOS IDWOS:000220151200004
Citation statistics
Cited Times:3[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://cas-ir.dicp.ac.cn/handle/321008/139374
Collection中国科学院大连化学物理研究所
AffiliationChinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Mol React Dynam, Dalian 116023, Peoples R China
Recommended Citation
GB/T 7714
Zhang, L,Zhang, M,Li, XC,et al. A new product channel in the energy transfer of CO (a, v ') plus NO(X)[J]. CHINESE JOURNAL OF CHEMICAL PHYSICS,2004,17(1):10-14.
APA Zhang, L,Zhang, M,Li, XC,Wang, XY,&Shen, GL.(2004).A new product channel in the energy transfer of CO (a, v ') plus NO(X).CHINESE JOURNAL OF CHEMICAL PHYSICS,17(1),10-14.
MLA Zhang, L,et al."A new product channel in the energy transfer of CO (a, v ') plus NO(X)".CHINESE JOURNAL OF CHEMICAL PHYSICS 17.1(2004):10-14.
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