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题名: Production of light alkenes with low CO2 emission from gas phase oxidative cracking (GOC) of hexane
作者: Liu, XB;  Li, WZ;  Xu, HY;  Chen, YX
关键词: gas phase oxidative cracking ;  hexane ;  light alkenes ;  carbon monoxide
刊名: REACTION KINETICS AND CATALYSIS LETTERS
发表日期: 2004
卷: 81, 期:2, 页:203-209
收录类别: SCI
文章类型: Article
WOS标题词: Science & Technology ;  Physical Sciences
类目[WOS]: Chemistry, Physical
研究领域[WOS]: Chemistry
英文摘要: Compared with non-oxidative pyrolysis of hexane, the rupture of C-C bonds of hexane in the GOC process becomes rather easy due to the change of thermodynamics and kinetics of the reaction with introduction of oxygen. CO predominates in the COx produced, and the ratio CO/CO2 can be as high as 16. The GOC process could be operated in an autothermic way, which would minimize energy consumption of the whole process and greatly decrease the CO2 emission. GOC seems to be an environmentally benign and promising alternative route for light alkenes production using heavy feedstock.
关键词[WOS]: PROMOTED OXIDE CATALYSTS ;  HETEROGENEOUS CONTRIBUTIONS ;  DEHYDROGENATION ;  ETHANE
语种: 英语
WOS记录号: WOS:000220510600001
Citation statistics: 
内容类型: 期刊论文
URI标识: http://cas-ir.dicp.ac.cn/handle/321008/139380
Appears in Collections:中国科学院大连化学物理研究所_期刊论文

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作者单位: 1.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Peoples R China

Recommended Citation:
Liu, XB,Li, WZ,Xu, HY,et al. Production of light alkenes with low CO2 emission from gas phase oxidative cracking (GOC) of hexane[J]. REACTION KINETICS AND CATALYSIS LETTERS,2004,81(2):203-209.
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