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题名: Study, on thermochemistry of room temperature ionic liquid 1. Solution enthalpy of EMIES and Pitzer's parameters
作者: Tan, ZC;  Zhang, ZH;  Sun, LX;  Xu, WG;  Xu, F;  Yang, JZ;  Zhang, T
关键词: room temperature ionic liquid ;  EMIES ;  solution enthalpy ;  apparent relative molar enthalpy ;  Pitzer's parameter ;  isoperibol calorimeter
刊名: ACTA CHIMICA SINICA
发表日期: 2004-11-14
卷: 62, 期:21, 页:2161-2164
收录类别: SCI
文章类型: Article
WOS标题词: Science & Technology ;  Physical Sciences
类目[WOS]: Chemistry, Multidisciplinary
研究领域[WOS]: Chemistry
英文摘要: Using the solution reaction isoperibol calorimeter, the molar solution enthalpies of room temperature ionic liquid, 1-ethyl-3-methylimidazolium ethyl sulfate (EMIES), with various molalities were determined at T = 303.150 K in water. According to Pitzer' s electrolyte solution theory, the molar solution enthalpy of EMIES at infinite dilution, Delta(s)H(m)(0), and Pitzer's parameters: beta(MX)((0)L), beta(MX)((1)L) and C-MX(phiL) were obtained. Then the values of apparent relative molar enthalpy L-phi, and relative partial molar enthalpy of solvent and solute (EMIES), (L) over bar (1) and (L) over bar (2) were calculated, respectively.
关键词[WOS]: CALORIMETER ;  CHLORIDE
语种: 英语
WOS记录号: WOS:000225048900006
Citation statistics: 
内容类型: 期刊论文
URI标识: http://cas-ir.dicp.ac.cn/handle/321008/139381
Appears in Collections:中国科学院大连化学物理研究所_期刊论文

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作者单位: 1.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Peoples R China
2.Liaoning Univ, Dept Chem, Shenyang 110036, Peoples R China

Recommended Citation:
Tan, ZC,Zhang, ZH,Sun, LX,et al. Study, on thermochemistry of room temperature ionic liquid 1. Solution enthalpy of EMIES and Pitzer's parameters[J]. ACTA CHIMICA SINICA,2004,62(21):2161-2164.
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