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THE DYNAMICS OF THE MOLECULAR BEAM REACTIONS Ba + C2H6Br, n-C3H1Br, 1,2-C2H4Br2, 1,3-C3H6Br2
Han Keli; Mo Yuxiang; He Guozhong; Lou Nanquan
刊名ACTA PHYSICO-CHIMICA SINICA
1990
DOI10.3866/PKU.WHXB19900324
6期:3页:375-380
收录类别SCI
文章类型Article
WOS标题词Science & Technology ; Physical Sciences
类目[WOS]Chemistry, Physical
研究领域[WOS]Chemistry
英文摘要Under single-collision beam-gas scattering conditions the reactions Ba + C2H6Br, n-C4H2Br, 1,2-C2H4Br2, 1,2,C3H2Br2 have been studied using laser induced fluorescence to letter the B2Br (XE+)-E-2 product. The vibrational distributions, the fractions of the available energy going into vibrational and rotational energy of the BaBr products have been calculated by means of computer simulation. It has been found that the average vibrational energies of the Bar products can be described as a linear function of the mass factors for the reactions Ba + CH2Br, C2H5Br, n-C3H7Br, 1,3- C3H6Br2, and that the potential energy surfaces for thesc reactions are similar. For the reactions Ba +CH3Br, C2H2Br, n-C2H7Br, the vibrational excitations of the BaBr products increase slightly when the number of the carbons increase, but for the reactions Ba + CH2Br2, 1,2-C2H4Br2, 1,3-C2H6Br2 the vibrational excitations of the BaBr products decrease greatly when the number of the cartons increase.
语种英语
WOS记录号WOS:000207572900024
引用统计
被引频次:1[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://cas-ir.dicp.ac.cn/handle/321008/139400
专题中国科学院大连化学物理研究所
作者单位CAS, Dalian Inst Chem Phys, Beijing, Peoples R China
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GB/T 7714
Han Keli,Mo Yuxiang,He Guozhong,et al. THE DYNAMICS OF THE MOLECULAR BEAM REACTIONS Ba + C2H6Br, n-C3H1Br, 1,2-C2H4Br2, 1,3-C3H6Br2[J]. ACTA PHYSICO-CHIMICA SINICA,1990,6(3):375-380.
APA Han Keli,Mo Yuxiang,He Guozhong,&Lou Nanquan.(1990).THE DYNAMICS OF THE MOLECULAR BEAM REACTIONS Ba + C2H6Br, n-C3H1Br, 1,2-C2H4Br2, 1,3-C3H6Br2.ACTA PHYSICO-CHIMICA SINICA,6(3),375-380.
MLA Han Keli,et al."THE DYNAMICS OF THE MOLECULAR BEAM REACTIONS Ba + C2H6Br, n-C3H1Br, 1,2-C2H4Br2, 1,3-C3H6Br2".ACTA PHYSICO-CHIMICA SINICA 6.3(1990):375-380.
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