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THE DYNAMICS OF THE MOLECULAR BEAM REACTIONS Ba + C2H6Br, n-C3H1Br, 1,2-C2H4Br2, 1,3-C3H6Br2
Han Keli; Mo Yuxiang; He Guozhong; Lou Nanquan
Source PublicationACTA PHYSICO-CHIMICA SINICA
1990
DOI10.3866/PKU.WHXB19900324
Volume6Issue:3Pages:375-380
Indexed BySCI
SubtypeArticle
WOS HeadingsScience & Technology ; Physical Sciences
WOS SubjectChemistry, Physical
WOS Research AreaChemistry
AbstractUnder single-collision beam-gas scattering conditions the reactions Ba + C2H6Br, n-C4H2Br, 1,2-C2H4Br2, 1,2,C3H2Br2 have been studied using laser induced fluorescence to letter the B2Br (XE+)-E-2 product. The vibrational distributions, the fractions of the available energy going into vibrational and rotational energy of the BaBr products have been calculated by means of computer simulation. It has been found that the average vibrational energies of the Bar products can be described as a linear function of the mass factors for the reactions Ba + CH2Br, C2H5Br, n-C3H7Br, 1,3- C3H6Br2, and that the potential energy surfaces for thesc reactions are similar. For the reactions Ba +CH3Br, C2H2Br, n-C2H7Br, the vibrational excitations of the BaBr products increase slightly when the number of the carbons increase, but for the reactions Ba + CH2Br2, 1,2-C2H4Br2, 1,3-C2H6Br2 the vibrational excitations of the BaBr products decrease greatly when the number of the cartons increase.
Language英语
WOS IDWOS:000207572900024
Citation statistics
Cited Times:1[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://cas-ir.dicp.ac.cn/handle/321008/139400
Collection中国科学院大连化学物理研究所
AffiliationCAS, Dalian Inst Chem Phys, Beijing, Peoples R China
Recommended Citation
GB/T 7714
Han Keli,Mo Yuxiang,He Guozhong,et al. THE DYNAMICS OF THE MOLECULAR BEAM REACTIONS Ba + C2H6Br, n-C3H1Br, 1,2-C2H4Br2, 1,3-C3H6Br2[J]. ACTA PHYSICO-CHIMICA SINICA,1990,6(3):375-380.
APA Han Keli,Mo Yuxiang,He Guozhong,&Lou Nanquan.(1990).THE DYNAMICS OF THE MOLECULAR BEAM REACTIONS Ba + C2H6Br, n-C3H1Br, 1,2-C2H4Br2, 1,3-C3H6Br2.ACTA PHYSICO-CHIMICA SINICA,6(3),375-380.
MLA Han Keli,et al."THE DYNAMICS OF THE MOLECULAR BEAM REACTIONS Ba + C2H6Br, n-C3H1Br, 1,2-C2H4Br2, 1,3-C3H6Br2".ACTA PHYSICO-CHIMICA SINICA 6.3(1990):375-380.
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