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THE H-1, C-13 NMR STUDIES ON ALKALOID PLATINUM(II) COMPLEXES
Yang Zhenyun; Han Xiuwen; Hu Jiehan; Chen Huilin
刊名ACTA PHYSICO-CHIMICA SINICA
1988
DOI10.3866/PKU.WHXB19880107
4期:1页:32-36
收录类别SCI
文章类型Article
WOS标题词Science & Technology ; Physical Sciences
类目[WOS]Chemistry, Physical
研究领域[WOS]Chemistry
英文摘要The C-13 and H-1 NMR spectra of antitumor alkaloid platinum complexes such as caffeine, theophylline and theobromine platinum (II)complexes were recorded. The H-1, C-13 chemical shifts and carbon hydrogen coupling conatants were obtained for these alkaloids and their platinum complexes. Compating the variations of 61, and 8c in, the Uganda before, and after coordination and combining with the determination of carbon platinum and hydrogen platinum coupling constants, we find that the alkaloids coordinate to platinum unidentately the coordination site is the double bond nitrogen atom on the five membered imidazole ring, The pla tinum (II) is coordinated with three chloride anions and one alkaloid ligand to form a mononuclear complex anion (PtLCl3)(-). By heterortuclear proton selected decoupling technique, all the H-1 and C-13 NUR spectral linen were assigned.
语种英语
WOS记录号WOS:000207571200007
引用统计
文献类型期刊论文
条目标识符http://cas-ir.dicp.ac.cn/handle/321008/139406
专题中国科学院大连化学物理研究所
作者单位Acad Sinica, Dalian Inst Chem Phys, Dalian, Peoples R China
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GB/T 7714
Yang Zhenyun,Han Xiuwen,Hu Jiehan,et al. THE H-1, C-13 NMR STUDIES ON ALKALOID PLATINUM(II) COMPLEXES[J]. ACTA PHYSICO-CHIMICA SINICA,1988,4(1):32-36.
APA Yang Zhenyun,Han Xiuwen,Hu Jiehan,&Chen Huilin.(1988).THE H-1, C-13 NMR STUDIES ON ALKALOID PLATINUM(II) COMPLEXES.ACTA PHYSICO-CHIMICA SINICA,4(1),32-36.
MLA Yang Zhenyun,et al."THE H-1, C-13 NMR STUDIES ON ALKALOID PLATINUM(II) COMPLEXES".ACTA PHYSICO-CHIMICA SINICA 4.1(1988):32-36.
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