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题名: THE DYNAMICS STUDIES OF REACTIONS Ca (S-1(0)) + CH2Cl2 CHCl3 AND Ca(P-3)+CH2Cl2, CHCl3
作者: Han Keli1;  He Guozhong1;  Lou Nanquan1
刊名: ACTA PHYSICO-CHIMICA SINICA
发表日期: 1988
DOI: 10.3866/PKU.WHXB19880619
卷: 4, 期:6, 页:660-664
收录类别: SCI
文章类型: Article
WOS标题词: Science & Technology ;  Physical Sciences
类目[WOS]: Chemistry, Physical
研究领域[WOS]: Chemistry
英文摘要: The reactions Ca(S-1(0)) + CH2Cl2 CHCl2 and Ca(P-3)+CH2Cl3, CHCl3 were studied by means of the laer induced fluorescence (LIF). Systematic simulation of the observed LW spectra revealed that change of the Ca atoms from the 3P states to the S-1(0) state brought about a decrease of the fraction of total energy going to the ground state CaCl product vibration and an increase of the fraction of total energy going to the ground state CaCl product rotation. Total cross sections for the reactions of Ca(S-1(0))+CH4-n Cl-n(n=2, 3)and the fraction of the Ca atoms going to the P-3 states in the discharge Ca beam were estimated from the LIF indensity of the CaCl product and total cross sections for the reactions Ca((3)p)+CH4-n Cl-2. They are 39 +/- 2 angstrom(3), 45 +/- 2 angstrom(2),1.8+0.1%, respectively.
语种: 英语
WOS记录号: WOS:000207571700019
Citation statistics: 
内容类型: 期刊论文
URI标识: http://cas-ir.dicp.ac.cn/handle/321008/139418
Appears in Collections:中国科学院大连化学物理研究所_期刊论文

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作者单位: 1.CAS, Dalian Inst Chem Phys, Dalian, Peoples R China

Recommended Citation:
Han Keli,He Guozhong,Lou Nanquan. THE DYNAMICS STUDIES OF REACTIONS Ca (S-1(0)) + CH2Cl2 CHCl3 AND Ca(P-3)+CH2Cl2, CHCl3[J]. ACTA PHYSICO-CHIMICA SINICA,1988,4(6):660-664.
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