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THE DYNAMICS STUDIES OF REACTIONS Ca (S-1(0)) + CH2Cl2 CHCl3 AND Ca(P-3)+CH2Cl2, CHCl3
Han Keli; He Guozhong; Lou Nanquan
刊名ACTA PHYSICO-CHIMICA SINICA
1988
DOI10.3866/PKU.WHXB19880619
4期:6页:660-664
收录类别SCI
文章类型Article
WOS标题词Science & Technology ; Physical Sciences
类目[WOS]Chemistry, Physical
研究领域[WOS]Chemistry
英文摘要The reactions Ca(S-1(0)) + CH2Cl2 CHCl2 and Ca(P-3)+CH2Cl3, CHCl3 were studied by means of the laer induced fluorescence (LIF). Systematic simulation of the observed LW spectra revealed that change of the Ca atoms from the 3P states to the S-1(0) state brought about a decrease of the fraction of total energy going to the ground state CaCl product vibration and an increase of the fraction of total energy going to the ground state CaCl product rotation. Total cross sections for the reactions of Ca(S-1(0))+CH4-n Cl-n(n=2, 3)and the fraction of the Ca atoms going to the P-3 states in the discharge Ca beam were estimated from the LIF indensity of the CaCl product and total cross sections for the reactions Ca((3)p)+CH4-n Cl-2. They are 39 +/- 2 angstrom(3), 45 +/- 2 angstrom(2),1.8+0.1%, respectively.
语种英语
WOS记录号WOS:000207571700019
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被引频次:3[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://cas-ir.dicp.ac.cn/handle/321008/139418
专题中国科学院大连化学物理研究所
作者单位CAS, Dalian Inst Chem Phys, Dalian, Peoples R China
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Han Keli,He Guozhong,Lou Nanquan. THE DYNAMICS STUDIES OF REACTIONS Ca (S-1(0)) + CH2Cl2 CHCl3 AND Ca(P-3)+CH2Cl2, CHCl3[J]. ACTA PHYSICO-CHIMICA SINICA,1988,4(6):660-664.
APA Han Keli,He Guozhong,&Lou Nanquan.(1988).THE DYNAMICS STUDIES OF REACTIONS Ca (S-1(0)) + CH2Cl2 CHCl3 AND Ca(P-3)+CH2Cl2, CHCl3.ACTA PHYSICO-CHIMICA SINICA,4(6),660-664.
MLA Han Keli,et al."THE DYNAMICS STUDIES OF REACTIONS Ca (S-1(0)) + CH2Cl2 CHCl3 AND Ca(P-3)+CH2Cl2, CHCl3".ACTA PHYSICO-CHIMICA SINICA 4.6(1988):660-664.
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