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题名: High Resolution Multiphoton Ionization Photoelectron Spectra of OCS
作者: Yang Dalin1;  Ding Chuanfan1;  Zhou You1;  Cai Hui1;  Zhu Qihe1
关键词: Carbonyl sulfide ;  Multiphoton ionization ;  Multiphoton ionization spectroscopy ;  Photoelectron spectroscopy
刊名: ACTA PHYSICO-CHIMICA SINICA
发表日期: 1994
DOI: 10.3866/PKU.WHXB19940913
卷: 10, 期:9, 页:838-840
收录类别: SCI
文章类型: Article
WOS标题词: Science & Technology ;  Physical Sciences
类目[WOS]: Chemistry, Physical
研究领域[WOS]: Chemistry
英文摘要: Using a Nd:YAG pumped pulsed dye laser wavelength extender as UV light source, the multiphoton ionization or OCS was studied in a supersonic molecular beam with a Time of Flight mass spectrometer and a Magnetic Bottle Time of Flight photoelectron spectrometer. The intermediate resonant states of OCS were obtained from the mass selected MPI spectra by scanning the laser wavelength. From 2+1 MPI photoelectron spectra at different resonant wavelength the vibrational levels of OCS+ ion in electronic ground state X-2 Pi(3/2,1/2) were assigned d their X-2 Pi spin orbital splitting was determined to be 0.046eV. The us Franck-Condon behavior between the Rydberg intermediate state and the ionic state has been discussed.
语种: 英语
WOS记录号: WOS:000207589600013
Citation statistics: 
内容类型: 期刊论文
URI标识: http://cas-ir.dicp.ac.cn/handle/321008/139422
Appears in Collections:中国科学院大连化学物理研究所_期刊论文

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作者单位: 1.Chinese Acad Sci, Inst Chem, State Key Lab Mol React Dynam, Beijing 100080, Peoples R China

Recommended Citation:
Yang Dalin,Ding Chuanfan,Zhou You,et al. High Resolution Multiphoton Ionization Photoelectron Spectra of OCS[J]. ACTA PHYSICO-CHIMICA SINICA,1994,10(9):838-840.
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