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THE STUDY OF THE REACTION RATE AND MECHANISM OF CN(V ''=0,1) RADICAL WITH HYDROCARBONS BY USING LASER INDUCED FLUORESCENCE METHOD
Li Xuechu1; Sayah, N.2; Jackson, W. M.2
刊名ACTA PHYSICO-CHIMICA SINICA
1988
DOI10.3866/PKU.WHXB19880217
4期:2页:205-211
收录类别SCI
文章类型Article
WOS标题词Science & Technology ; Physical Sciences
类目[WOS]Chemistry, Physical
研究领域[WOS]Chemistry
英文摘要The rate constants of eleven hydrocarbons and fluorocarbons with CN (V"=0, 1) at 300K have been measured by using Laser Induced Fluorescence(LIF) method. For the saturated hydrocarbons, the rate constants are chagned from (5.6 +/- 0.3) x 10(-13) for CH4 to (2.3 + 0.2) x 10(-10)cm(3) molecu(-1),8(-1) for C7H16. The rate constants of the reaction of CN with alkenes and alkynes are close to the gas kinetic rate in spite of the structure of the molecules. The rate constants and mechanism of CN with the saturated hydrocarbons, H-2 and CH3OH can be explained satisfactorily by the long distance attractive potential. The reaction of CN with alkenes and alkynes can only proceed through the addition into pi bond. The influence of vibrational energy on the reaction rate was not found in the reactions of CN radical with hydrocarbon compounds.
语种英语
WOS记录号WOS:000207571300016
引用统计
文献类型期刊论文
条目标识符http://cas-ir.dicp.ac.cn/handle/321008/139434
专题中国科学院大连化学物理研究所
作者单位1.Chinese Acad Sci, Dalian Inst Chem Phys, Beijing 100864, Peoples R China
2.Howard Univ, Dept Chem, Washington, DC 20059 USA
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Li Xuechu,Sayah, N.,Jackson, W. M.. THE STUDY OF THE REACTION RATE AND MECHANISM OF CN(V ''=0,1) RADICAL WITH HYDROCARBONS BY USING LASER INDUCED FLUORESCENCE METHOD[J]. ACTA PHYSICO-CHIMICA SINICA,1988,4(2):205-211.
APA Li Xuechu,Sayah, N.,&Jackson, W. M..(1988).THE STUDY OF THE REACTION RATE AND MECHANISM OF CN(V ''=0,1) RADICAL WITH HYDROCARBONS BY USING LASER INDUCED FLUORESCENCE METHOD.ACTA PHYSICO-CHIMICA SINICA,4(2),205-211.
MLA Li Xuechu,et al."THE STUDY OF THE REACTION RATE AND MECHANISM OF CN(V ''=0,1) RADICAL WITH HYDROCARBONS BY USING LASER INDUCED FLUORESCENCE METHOD".ACTA PHYSICO-CHIMICA SINICA 4.2(1988):205-211.
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