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Studies on Cu-ZnO/Al2O3 catalyst for hydrogen production via autothermal reforming of methanol
Li, SL; Chen, GW; Jiao, FJ; Li, HQ
关键词Methanol Autothermal Reforming Hydrogen Copper Zinc Oxide Alumina Cordierite Ceramic
刊名CHINESE JOURNAL OF CATALYSIS
2004-12-01
25期:12页:979-982
收录类别SCI
文章类型Article
WOS标题词Science & Technology ; Physical Sciences ; Technology
类目[WOS]Chemistry, Applied ; Chemistry, Physical ; Engineering, Chemical
研究领域[WOS]Chemistry ; Engineering
关键词[WOS]SELECTIVE PRODUCTION
英文摘要The Cu-ZnO/Al2O3 catalyst supported on monolithic cordierite substrate for production of hydrogen via methanol autothermal reforming was prepared by co-precipitation method and characterized by XRD and H-2- TPR. The effects of Cu loading and reaction conditions on the catalyst activity and reaction rate were Investigated. The results showed that low Cu loading was in favor of the reduction and uniform distribution of the catalyst. The addition of gamma-Al2O3 promoted the reduction of Cu. The higher H, production rate and CO2 selectivity were obtained under the conditions of the Cu loading of 20% similar to 60 %, molar ratio of O-2 to methanol of 0.3. and gas hourly space velocity based on methanol of 4 000 similar to 12 000 h(-1). The reduced Cu is the active site for the methanol autothermal reforming.
语种英语
WOS记录号WOS:000226325900011
引用统计
被引频次:8[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://cas-ir.dicp.ac.cn/handle/321008/139503
专题中国科学院大连化学物理研究所
作者单位Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Peoples R China
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GB/T 7714
Li, SL,Chen, GW,Jiao, FJ,et al. Studies on Cu-ZnO/Al2O3 catalyst for hydrogen production via autothermal reforming of methanol[J]. CHINESE JOURNAL OF CATALYSIS,2004,25(12):979-982.
APA Li, SL,Chen, GW,Jiao, FJ,&Li, HQ.(2004).Studies on Cu-ZnO/Al2O3 catalyst for hydrogen production via autothermal reforming of methanol.CHINESE JOURNAL OF CATALYSIS,25(12),979-982.
MLA Li, SL,et al."Studies on Cu-ZnO/Al2O3 catalyst for hydrogen production via autothermal reforming of methanol".CHINESE JOURNAL OF CATALYSIS 25.12(2004):979-982.
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