DICP OpenIR
Ultra-deep desulfurization of diesel: Oxidation with a recoverable catalyst assembled in emulsion
Li, C; Jiang, ZX; Gao, JB; Yang, YX; Wang, SJ; Tian, FP; Sun, FX; Sun, XP; Ying, PL; Han, CR
关键词Desulfurization Diesel Emulsion Green Chemistry Oxidation
刊名CHEMISTRY-A EUROPEAN JOURNAL
2004-05-03
DOI10.1002/chem.200305679
10期:9页:2277-2280
收录类别SCI
文章类型Article
WOS标题词Science & Technology ; Physical Sciences
类目[WOS]Chemistry, Multidisciplinary
研究领域[WOS]Chemistry
关键词[WOS]HYDROGEN-PEROXIDE ; FUEL-CELLS ; DIBENZOTHIOPHENES ; ADSORPTION ; ZEOLITES ; OILS
英文摘要can be lowered from about 500 ppm to 0.1 ppm without changing the properties of the diesel. The catalyst demonstrates high performance ( greater than or equal to 96% efficiency of H2O2, is easily recycled, andA [(C18H37)(2)N+ (CH3)(2)](3)[PW12O40] catalyst, assembled in an emulsion in diesel, can selectively oxidize the sulfur-containing molecules present in diesel into their corresponding sulfones by using H2O2 as the oxidant under mild conditions. The sultones can be readily separated from the diesel using an extractant, and the sulfur level of the desulfurized diesel similar to100% selectivity to sulfones). Metastable emulsion droplets (water in oil) act like a homogeneous catalyst and are formed when the catalyst (as the surfactant) and H2O2 (30%) are mixed in the diesel. However, the catalyst can be separated from the diesel after demulsification.
语种英语
WOS记录号WOS:000221275300019
引用统计
被引频次:208[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://cas-ir.dicp.ac.cn/handle/321008/139556
专题中国科学院大连化学物理研究所
作者单位1.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Peoples R China
2.SINOPEC, Fushun Res Inst Petr & Petrochem, Liaoning 113001, Peoples R China
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GB/T 7714
Li, C,Jiang, ZX,Gao, JB,et al. Ultra-deep desulfurization of diesel: Oxidation with a recoverable catalyst assembled in emulsion[J]. CHEMISTRY-A EUROPEAN JOURNAL,2004,10(9):2277-2280.
APA Li, C.,Jiang, ZX.,Gao, JB.,Yang, YX.,Wang, SJ.,...&Han, CR.(2004).Ultra-deep desulfurization of diesel: Oxidation with a recoverable catalyst assembled in emulsion.CHEMISTRY-A EUROPEAN JOURNAL,10(9),2277-2280.
MLA Li, C,et al."Ultra-deep desulfurization of diesel: Oxidation with a recoverable catalyst assembled in emulsion".CHEMISTRY-A EUROPEAN JOURNAL 10.9(2004):2277-2280.
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