中国科学院大连化学物理研究所机构知识库
Advanced  
DICP OpenIR  > 中国科学院大连化学物理研究所  > 期刊论文
题名: Heteropoly blue as a reaction-controlled phase-transfer catalyst for the epoxidation of olefins
作者: Li, MQ;  Jian, XG
刊名: BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN
发表日期: 2005-08-15
卷: 78, 期:8, 页:1575-1579
收录类别: SCI ;  CCR
文章类型: Article
WOS标题词: Science & Technology ;  Physical Sciences
类目[WOS]: Chemistry, Multidisciplinary
研究领域[WOS]: Chemistry
英文摘要: A new reaction-controlled phase-transfer catalyst system has been designed and synthesized. In this system, heteropoly blue, [C7H7N(CH3)(3)](3)PMo4O16, is used for the catalytic epoxidation of olefins with H2O2 as the oxidant. In this system, the catalyst not only can be recovered, like heterogeneous catalyst, but also acts as a homogeneous catalyst. The main products are epoxide of olefins and H2O; no co-product forms. The system exhibits high conversion and selectivity as well as excellent catalyst stability. (PNMR)-P-31 spectra, UV-vis spectra, and infrared spectra are used to analyze the reason for the phase transfer of the catalyst, indicating that the change of structure leads to the formation of reaction-controlled phase-transfer catalyst.
关键词[WOS]: HYDROGEN-PEROXIDE ;  OXIDATION ;  COMPLEXES ;  ALCOHOLS ;  ALKENES ;  SYSTEMS ;  OXIDE
语种: 英语
WOS记录号: WOS:000231523300026
Citation statistics: 
内容类型: 期刊论文
URI标识: http://cas-ir.dicp.ac.cn/handle/321008/139627
Appears in Collections:中国科学院大连化学物理研究所_期刊论文

Files in This Item:

There are no files associated with this item.


作者单位: 1.Dalian Univ Technol, Dept Polymer Sci & Mat, Dalian 116012, Peoples R China
2.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Peoples R China

Recommended Citation:
Li, MQ,Jian, XG. Heteropoly blue as a reaction-controlled phase-transfer catalyst for the epoxidation of olefins[J]. BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN,2005,78(8):1575-1579.
Service
 Recommend this item
 Sava as my favorate item
 Show this item's statistics
 Export Endnote File
Google Scholar
 Similar articles in Google Scholar
 [Li, MQ]'s Articles
 [Jian, XG]'s Articles
CSDL cross search
 Similar articles in CSDL Cross Search
 [Li, MQ]‘s Articles
 [Jian, XG]‘s Articles
Related Copyright Policies
Null
Social Bookmarking
  Add to CiteULike  Add to Connotea  Add to Del.icio.us  Add to Digg  Add to Reddit 
所有评论 (0)
暂无评论
 
评注功能仅针对注册用户开放,请您登录
您对该条目有什么异议,请填写以下表单,管理员会尽快联系您。
内 容:
Email:  *
单位:
验证码:   刷新
您在IR的使用过程中有什么好的想法或者建议可以反馈给我们。
标 题:
 *
内 容:
Email:  *
验证码:   刷新

Items in IR are protected by copyright, with all rights reserved, unless otherwise indicated.

 

 

Valid XHTML 1.0!
Powered by CSpace