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Heteropoly blue as a reaction-controlled phase-transfer catalyst for the epoxidation of olefins
Li, MQ; Jian, XG
刊名BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN
2005-08-15
78期:8页:1575-1579
收录类别SCI ; CCR
文章类型Article
WOS标题词Science & Technology ; Physical Sciences
类目[WOS]Chemistry, Multidisciplinary
研究领域[WOS]Chemistry
关键词[WOS]HYDROGEN-PEROXIDE ; OXIDATION ; COMPLEXES ; ALCOHOLS ; ALKENES ; SYSTEMS ; OXIDE
英文摘要A new reaction-controlled phase-transfer catalyst system has been designed and synthesized. In this system, heteropoly blue, [C7H7N(CH3)(3)](3)PMo4O16, is used for the catalytic epoxidation of olefins with H2O2 as the oxidant. In this system, the catalyst not only can be recovered, like heterogeneous catalyst, but also acts as a homogeneous catalyst. The main products are epoxide of olefins and H2O; no co-product forms. The system exhibits high conversion and selectivity as well as excellent catalyst stability. (PNMR)-P-31 spectra, UV-vis spectra, and infrared spectra are used to analyze the reason for the phase transfer of the catalyst, indicating that the change of structure leads to the formation of reaction-controlled phase-transfer catalyst.
语种英语
WOS记录号WOS:000231523300026
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被引频次:6[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://cas-ir.dicp.ac.cn/handle/321008/139627
专题中国科学院大连化学物理研究所
作者单位1.Dalian Univ Technol, Dept Polymer Sci & Mat, Dalian 116012, Peoples R China
2.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Peoples R China
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GB/T 7714
Li, MQ,Jian, XG. Heteropoly blue as a reaction-controlled phase-transfer catalyst for the epoxidation of olefins[J]. BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN,2005,78(8):1575-1579.
APA Li, MQ,&Jian, XG.(2005).Heteropoly blue as a reaction-controlled phase-transfer catalyst for the epoxidation of olefins.BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN,78(8),1575-1579.
MLA Li, MQ,et al."Heteropoly blue as a reaction-controlled phase-transfer catalyst for the epoxidation of olefins".BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN 78.8(2005):1575-1579.
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