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Practical Rh(I)-catalyzed asymmetric hydrogenation of beta-(acylamino)acrylates using a new unsymmetrical hybrid ferrocenylphosphine-phosphoramidite ligand: Crucial influence of an N-H proton in the ligand
Hu, XP; Zhuo, Z
Source PublicationORGANIC LETTERS
2005-02-03
DOI10.1021/ol047748x
Volume7Issue:3Pages:419-422
Indexed BySCI ; IC ; CCR
SubtypeArticle
WOS HeadingsScience & Technology ; Physical Sciences
WOS SubjectChemistry, Organic
WOS Research AreaChemistry
WOS KeywordBETA-AMINO ACIDS ; HIGHLY ENANTIOSELECTIVE HYDROGENATION ; RHODIUM-CATALYZED HYDROGENATION ; SUBSTITUTED BETA-(ACYLAMINO)ACRYLATES ; MONODENTATE PHOSPHORAMIDITES ; MONOPHOSPHITE LIGANDS ; ALLYLIC ALKYLATION ; DIPHOSPHINE LIGAND ; IMINE LIGANDS ; DERIVATIVES
AbstractExcellent enantioselectivities and high turnovers (S/C = 5000) were achieved in the Rh(l)-catalyzed asymmetric hydrogenation of both beta-aryl-and beta-alkyl-beta-(acylamino)acrylates with a new unsymmetrical hybrid ferrocenylphosphine-phosphoramidite ligand, and the presence of an N-H proton in the ligand was demonstrated to have a crucial role in the enantioselectivity.
Language英语
WOS IDWOS:000226679100016
Citation statistics
Cited Times:64[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://cas-ir.dicp.ac.cn/handle/321008/139633
Collection中国科学院大连化学物理研究所
AffiliationChinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Peoples R China
Recommended Citation
GB/T 7714
Hu, XP,Zhuo, Z. Practical Rh(I)-catalyzed asymmetric hydrogenation of beta-(acylamino)acrylates using a new unsymmetrical hybrid ferrocenylphosphine-phosphoramidite ligand: Crucial influence of an N-H proton in the ligand[J]. ORGANIC LETTERS,2005,7(3):419-422.
APA Hu, XP,&Zhuo, Z.(2005).Practical Rh(I)-catalyzed asymmetric hydrogenation of beta-(acylamino)acrylates using a new unsymmetrical hybrid ferrocenylphosphine-phosphoramidite ligand: Crucial influence of an N-H proton in the ligand.ORGANIC LETTERS,7(3),419-422.
MLA Hu, XP,et al."Practical Rh(I)-catalyzed asymmetric hydrogenation of beta-(acylamino)acrylates using a new unsymmetrical hybrid ferrocenylphosphine-phosphoramidite ligand: Crucial influence of an N-H proton in the ligand".ORGANIC LETTERS 7.3(2005):419-422.
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