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题名: Photo-induced intra-complex reactions in Ca+-NH2C(CH3)(3)
作者: Wang, DS;  Han, KL;  Yang, SH
关键词: complex ;  photodissociation ;  atomic orbital ;  action spectrum
刊名: ACTA PHYSICO-CHIMICA SINICA
发表日期: 2005-06-01
DOI: 10.3866/PKU.WHXB20050601
卷: 21, 期:6, 页:583-585
收录类别: SCI
文章类型: Article
WOS标题词: Science & Technology ;  Physical Sciences
类目[WOS]: Chemistry, Physical
研究领域[WOS]: Chemistry
英文摘要: Laser induced reaction of Ca+- tertbutylamine complex was studied by reflection time of flight spectrum (RTOF). Different photodissociation spectra, the action spectrum as function of laser wavelength, and ratio curve of different channels were obtained. Two channels were found, one was Ca+ cation separation channel, the other one was reactive channel for product Ca+NH2. Product Ca+ was dominant in the whole region studied and the only one in the region 530 similar to 595 nm. The action spectrum shows pronounced structureless peaks, which are relevant to the transition of complex. The dynamics of the reaction was discussed at the end.
关键词[WOS]: EARTH METAL-IONS ;  GAS-PHASE ;  PHOTODISSOCIATION SPECTROSCOPY ;  ANIONIC PEPTIDES ;  BINDING ;  DECOMPOSITION ;  DIPEPTIDES ;  ENERGIES ;  MODELS ;  N=1-4
语种: 英语
WOS记录号: WOS:000230129500001
Citation statistics: 
内容类型: 期刊论文
URI标识: http://cas-ir.dicp.ac.cn/handle/321008/139649
Appears in Collections:中国科学院大连化学物理研究所_期刊论文

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作者单位: 1.Hong Kong Univ Sci & Technol, Dept Chem, Kowloon, Hong Kong, Peoples R China
2.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Mol React Dynam, Dalian 116023, Peoples R China

Recommended Citation:
Wang, DS,Han, KL,Yang, SH. Photo-induced intra-complex reactions in Ca+-NH2C(CH3)(3)[J]. ACTA PHYSICO-CHIMICA SINICA,2005,21(6):583-585.
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