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New unsymmetrical hybrid ferrocenylphosphine-phosphoramidite ligands derived from H-8-BINOL for highly efficient Rh-catalyzed enantioselective hydrogenation
Zeng, QH; Hu, XP; Duan, ZC; Liang, XM; Zheng, Z
刊名TETRAHEDRON-ASYMMETRY
2005-03-21
DOI10.1016/j.tetasy.2005.02.003
16期:6页:1233-1238
收录类别SCI ; IC
文章类型Article
WOS标题词Science & Technology ; Physical Sciences
类目[WOS]Chemistry, Inorganic & Nuclear ; Chemistry, Organic ; Chemistry, Physical
研究领域[WOS]Chemistry
关键词[WOS]ASYMMETRIC HYDROGENATION ; ALLYLIC ALKYLATION ; PHOSPHORUS LIGANDS ; PRACTICAL LIGANDS ; RHODIUM CATALYST ; IMINE LIGANDS ; 1,1'-BINAPHTHYL ; KETONES ; BINOL
英文摘要A series of new H-8-BINOL-derived unsymmetrical hybrid ferrocenylphosphine-phosphoramidite ligands have been synthesized and successfully used in Rh-catalyzed asymmetric hydrogenations. The same or higher enantioselectivities (99.9% ee) were achieved in the hydrogenation of dimethyl itaconate and alpha-dehydroamino acid esters as those obtained with BINOL-derived analogues. However, slightly lower enantioselectivities (99.0% ee) were obtained in the hydrogenation of enamides. (C) 2005 Elsevier Ltd. All rights reserved.
语种英语
WOS记录号WOS:000227973600020
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被引频次:41[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://cas-ir.dicp.ac.cn/handle/321008/139670
专题中国科学院大连化学物理研究所
作者单位1.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Peoples R China
2.Chinese Acad Sci, Grad Sch, Beijing 100039, Peoples R China
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GB/T 7714
Zeng, QH,Hu, XP,Duan, ZC,et al. New unsymmetrical hybrid ferrocenylphosphine-phosphoramidite ligands derived from H-8-BINOL for highly efficient Rh-catalyzed enantioselective hydrogenation[J]. TETRAHEDRON-ASYMMETRY,2005,16(6):1233-1238.
APA Zeng, QH,Hu, XP,Duan, ZC,Liang, XM,&Zheng, Z.(2005).New unsymmetrical hybrid ferrocenylphosphine-phosphoramidite ligands derived from H-8-BINOL for highly efficient Rh-catalyzed enantioselective hydrogenation.TETRAHEDRON-ASYMMETRY,16(6),1233-1238.
MLA Zeng, QH,et al."New unsymmetrical hybrid ferrocenylphosphine-phosphoramidite ligands derived from H-8-BINOL for highly efficient Rh-catalyzed enantioselective hydrogenation".TETRAHEDRON-ASYMMETRY 16.6(2005):1233-1238.
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