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题名: Application of ferrocene-derived chiral S,P-donor ligands for iridium-catalyzed asymmetric hydrogenation of quinolines
作者: Zhao, YJ;  Wang, YQ;  Zhou, YG
关键词: ferrocene ;  chiral S,P-donor ligand ;  iridium ;  quinoline ;  asymmetric hydrogenation
刊名: CHINESE JOURNAL OF CATALYSIS
发表日期: 2005-09-01
卷: 26, 期:9, 页:737-739
收录类别: SCI
文章类型: Article
WOS标题词: Science & Technology ;  Physical Sciences ;  Technology
类目[WOS]: Chemistry, Applied ;  Chemistry, Physical ;  Engineering, Chemical
研究领域[WOS]: Chemistry ;  Engineering
英文摘要: Chiral S,P-donor ferrocene-derived ligands were synthesized and applied in the asymmetric hydrogenation of quinolines using the [Ir(COD)Cl](2)/S, P-ligand complex as the catalyst in the presence of iodine. The effects of the solvent and hydrogen pressure on conversion and enantioselectivity were examined, and up to 82% ee was obtained. The planar chirality plays an important role in this reaction. R- and S-enantiomers of 1 2,3,4-tetrahydroquinoline derivatives were obtained using ligands 3 and 5, respectively.
关键词[WOS]: HYDROSILYLATION ;  BACKBONE
语种: 英语
WOS记录号: WOS:000232474800004
Citation statistics: 
内容类型: 期刊论文
URI标识: http://cas-ir.dicp.ac.cn/handle/321008/139711
Appears in Collections:中国科学院大连化学物理研究所_期刊论文

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作者单位: 1.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Peoples R China

Recommended Citation:
Zhao, YJ,Wang, YQ,Zhou, YG. Application of ferrocene-derived chiral S,P-donor ligands for iridium-catalyzed asymmetric hydrogenation of quinolines[J]. CHINESE JOURNAL OF CATALYSIS,2005,26(9):737-739.
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