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题名: Synthesis of novel monophosphoramidite ligands derived from L-proline for Rh-catalyzed asymmetric hydrogenation of alpha-dehydroamino acid esters
作者: Zeng, QH;  Hu, XP;  Liang, XM;  Zheng, Z
关键词: monophosphoramidite ;  L-proline ;  Rh-catalyzed asymmetric hydrogenation ;  alpha-dehydroamino acid
刊名: CHINESE CHEMICAL LETTERS
发表日期: 2005-10-01
卷: 16, 期:10, 页:1321-1323
收录类别: SCI
文章类型: Article
WOS标题词: Science & Technology ;  Physical Sciences
类目[WOS]: Chemistry, Multidisciplinary
研究领域[WOS]: Chemistry
英文摘要: Two novel monophosphoramidites were synthesized through a five-step transformation from commercially available L-proline. In the Rh-catalyzed asymmetric hydrogenation of alpha-dehydroamino acid derivatives, ligand (S-C,R-a)-lb showed good enantioselectivity and up to 91% e.e. was obtained.
关键词[WOS]: MONODENTATE PHOSPHORUS LIGANDS ;  ENANTIOSELECTIVE HYDROGENATION
语种: 英语
WOS记录号: WOS:000232638500012
Citation statistics: 
内容类型: 期刊论文
URI标识: http://cas-ir.dicp.ac.cn/handle/321008/139746
Appears in Collections:中国科学院大连化学物理研究所_期刊论文

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作者单位: 1.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Peoples R China
2.Chinese Acad Sci, Grad Sch, Beijing 100039, Peoples R China

Recommended Citation:
Zeng, QH,Hu, XP,Liang, XM,et al. Synthesis of novel monophosphoramidite ligands derived from L-proline for Rh-catalyzed asymmetric hydrogenation of alpha-dehydroamino acid esters[J]. CHINESE CHEMICAL LETTERS,2005,16(10):1321-1323.
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