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Gas-phase reactions of V+ and VO+ with methanol
Cao, YL; Zhao, X; Tang, ZC; Xin, B; Xiong, SX
关键词Reactivity Ft-icr Mass Spectrometer Ab Initio Calculation
刊名INTERNATIONAL JOURNAL OF MODERN PHYSICS B
2005-07-10
19期:15-17页:2693-2698
收录类别ISTP ; SCI
文章类型Article
WOS标题词Science & Technology ; Physical Sciences
类目[WOS]Physics, Applied ; Physics, Condensed Matter ; Physics, Mathematical
研究领域[WOS]Physics
关键词[WOS]OXIDE CLUSTER CATIONS ; BOND-ENERGIES ; METAL-IONS ; VANADIUM ; OXIDATION ; M+ ; CATALYSTS ; CHEMISTRY ; ALCOHOLS ; CO
英文摘要The reactions of V+ and VO+ with methanol have been investigated experimentally by FT-ICR mass spectrometer and theoretically by ab initio calculation. Both V+ and VO+ exhibit impressive reactivity with methanol. The products distribution of different reaction time indicate that in whole reaction processes methanol is adsorbed one by one, and no more than four methanol molecules can be solved in the first shell of central ion V+. The reaction mechanisms have been proposed, and the possible geometrical structures of products are also analyzed by DFT calculations.
语种英语
WOS记录号WOS:000231237600014
引用统计
文献类型期刊论文
条目标识符http://cas-ir.dicp.ac.cn/handle/321008/139800
专题中国科学院大连化学物理研究所
作者单位1.Chinese Acad Sci, Inst Chem, State Key Lab Mol React Dynam, Beijing 100080, Peoples R China
2.Chinese Acad Sci, Inst Chem, Ctr Mass Sepctrometry, Beijing 100080, Peoples R China
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GB/T 7714
Cao, YL,Zhao, X,Tang, ZC,et al. Gas-phase reactions of V+ and VO+ with methanol[J]. INTERNATIONAL JOURNAL OF MODERN PHYSICS B,2005,19(15-17):2693-2698.
APA Cao, YL,Zhao, X,Tang, ZC,Xin, B,&Xiong, SX.(2005).Gas-phase reactions of V+ and VO+ with methanol.INTERNATIONAL JOURNAL OF MODERN PHYSICS B,19(15-17),2693-2698.
MLA Cao, YL,et al."Gas-phase reactions of V+ and VO+ with methanol".INTERNATIONAL JOURNAL OF MODERN PHYSICS B 19.15-17(2005):2693-2698.
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