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Asymmetric epoxidation of unfunctionalized olefins catalyzed by Mn(salen) axially immobilized onto insoluble polymers
Zhang, HD; Zhang, YM; Li, C
刊名TETRAHEDRON-ASYMMETRY
2005-07-18
DOI10.1016/j.tetasy.2005.05.034
16期:14页:2417-2423
收录类别SCI ; IC ; CCR
文章类型Article
WOS标题词Science & Technology ; Physical Sciences
类目[WOS]Chemistry, Inorganic & Nuclear ; Chemistry, Organic ; Chemistry, Physical
研究领域[WOS]Chemistry
关键词[WOS]HETEROGENEOUS ENANTIOSELECTIVE CATALYST ; SALEN COMPLEXES ; STYRENE ; MN ; ALKENES ; COPOLYMERIZATION ; POLYSTYRENE ; ALDEHYDES ; CARBON ; CLAY
英文摘要Chiral Mn(salen) complexes axially immobilized onto insoluble polymers by phenoxy group or phenyl sulfonic group afford comparable or even higher enantioselectivities than homogeneous Mn(salen) catalysts for the asymmetric epoxidation of various unfunctionalized olefins. These heterogeneous Mn(salen) catalysts are relatively stable and can be recycled in the asymmetric epoxidation. (C) 2005 Published by Elsevier Ltd.
语种英语
WOS记录号WOS:000231209800008
引用统计
文献类型期刊论文
条目标识符http://cas-ir.dicp.ac.cn/handle/321008/139801
专题中国科学院大连化学物理研究所
作者单位Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Peoples R China
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GB/T 7714
Zhang, HD,Zhang, YM,Li, C. Asymmetric epoxidation of unfunctionalized olefins catalyzed by Mn(salen) axially immobilized onto insoluble polymers[J]. TETRAHEDRON-ASYMMETRY,2005,16(14):2417-2423.
APA Zhang, HD,Zhang, YM,&Li, C.(2005).Asymmetric epoxidation of unfunctionalized olefins catalyzed by Mn(salen) axially immobilized onto insoluble polymers.TETRAHEDRON-ASYMMETRY,16(14),2417-2423.
MLA Zhang, HD,et al."Asymmetric epoxidation of unfunctionalized olefins catalyzed by Mn(salen) axially immobilized onto insoluble polymers".TETRAHEDRON-ASYMMETRY 16.14(2005):2417-2423.
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