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题名: Asymmetric epoxidation of unfunctionalized olefins catalyzed by Mn(salen) axially immobilized onto insoluble polymers
作者: Zhang, HD;  Zhang, YM;  Li, C
刊名: TETRAHEDRON-ASYMMETRY
发表日期: 2005-07-18
DOI: 10.1016/j.tetasy.2005.05.034
卷: 16, 期:14, 页:2417-2423
收录类别: SCI ;  IC ;  CCR
文章类型: Article
WOS标题词: Science & Technology ;  Physical Sciences
类目[WOS]: Chemistry, Inorganic & Nuclear ;  Chemistry, Organic ;  Chemistry, Physical
研究领域[WOS]: Chemistry
英文摘要: Chiral Mn(salen) complexes axially immobilized onto insoluble polymers by phenoxy group or phenyl sulfonic group afford comparable or even higher enantioselectivities than homogeneous Mn(salen) catalysts for the asymmetric epoxidation of various unfunctionalized olefins. These heterogeneous Mn(salen) catalysts are relatively stable and can be recycled in the asymmetric epoxidation. (C) 2005 Published by Elsevier Ltd.
关键词[WOS]: HETEROGENEOUS ENANTIOSELECTIVE CATALYST ;  SALEN COMPLEXES ;  STYRENE ;  MN ;  ALKENES ;  COPOLYMERIZATION ;  POLYSTYRENE ;  ALDEHYDES ;  CARBON ;  CLAY
语种: 英语
WOS记录号: WOS:000231209800008
Citation statistics: 
内容类型: 期刊论文
URI标识: http://cas-ir.dicp.ac.cn/handle/321008/139801
Appears in Collections:中国科学院大连化学物理研究所_期刊论文

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作者单位: 1.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Peoples R China

Recommended Citation:
Zhang, HD,Zhang, YM,Li, C. Asymmetric epoxidation of unfunctionalized olefins catalyzed by Mn(salen) axially immobilized onto insoluble polymers[J]. TETRAHEDRON-ASYMMETRY,2005,16(14):2417-2423.
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