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Synthesis and highly enantioselective hydrogenation of exocyclic enamides: (Z)-3-arylidene-4-acetyl-3,4-dihydro-2H-1,4-benzoxazines
Zhou, YG; Yang, PY; Han, XW
刊名JOURNAL OF ORGANIC CHEMISTRY
2005-03-04
DOI10.1021/jo048212s
70期:5页:1679-1683
收录类别SCI ; IC
文章类型Article
WOS标题词Science & Technology ; Physical Sciences
类目[WOS]Chemistry, Organic
研究领域[WOS]Chemistry
关键词[WOS]RH-CATALYZED HYDROGENATIONS ; ASYMMETRIC-SYNTHESIS ; KINETIC RESOLUTION ; KEY INTERMEDIATE ; 2 HETEROATOMS ; STEREOSELECTIVE-SYNTHESIS ; HETEROCYCLIC STRUCTURES ; ISOQUINOLINE ALKALOIDS ; FACILE SYNTHESIS ; CYCLIC ENAMIDES
英文摘要Highly enantioselective hydrogenation of exocyclic enamides, (Z)-3-arylidene-4-acyl-3,4-dihydro-2H-benzoxazines, was achieved in up to 98.6% ee by using Rh/(R,R)-Me-Duphos complex as the catalytic system. The absolute configuration of the product was assigned as R by chemical interrelations.
语种英语
WOS记录号WOS:000227246800020
引用统计
被引频次:61[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://cas-ir.dicp.ac.cn/handle/321008/139810
专题中国科学院大连化学物理研究所
作者单位Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Peoples R China
推荐引用方式
GB/T 7714
Zhou, YG,Yang, PY,Han, XW. Synthesis and highly enantioselective hydrogenation of exocyclic enamides: (Z)-3-arylidene-4-acetyl-3,4-dihydro-2H-1,4-benzoxazines[J]. JOURNAL OF ORGANIC CHEMISTRY,2005,70(5):1679-1683.
APA Zhou, YG,Yang, PY,&Han, XW.(2005).Synthesis and highly enantioselective hydrogenation of exocyclic enamides: (Z)-3-arylidene-4-acetyl-3,4-dihydro-2H-1,4-benzoxazines.JOURNAL OF ORGANIC CHEMISTRY,70(5),1679-1683.
MLA Zhou, YG,et al."Synthesis and highly enantioselective hydrogenation of exocyclic enamides: (Z)-3-arylidene-4-acetyl-3,4-dihydro-2H-1,4-benzoxazines".JOURNAL OF ORGANIC CHEMISTRY 70.5(2005):1679-1683.
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