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题名: 2,6-bis(3,5-dimethylpyrazol-1-yl)pyridine: A useful pseudo-N-3 ligand in efficient ruthenium(II)-catalyzed transfer hydrogenation of ketones
作者: Deng, HX;  Yu, ZK;  Dong, JH;  Wu, SZ
刊名: ORGANOMETALLICS
发表日期: 2005-08-15
DOI: 10.1021/om050467o
卷: 24, 期:17, 页:4110-4112
收录类别: SCI ;  CCR
文章类型: Article
WOS标题词: Science & Technology ;  Physical Sciences
类目[WOS]: Chemistry, Inorganic & Nuclear ;  Chemistry, Organic
研究领域[WOS]: Chemistry
英文摘要: Transfer hydrogenation of ketones was efficiently carried out with a ruthenium(II) complex bearing the ligand 2,6-bis(3,5-dimethylpyrazol-1-yl)pyridine (Me(4)BPFy), i.e., RuCl2(PPh3)(Me(4)BPFy), in 2-propanol at 82 degrees C. The single-crystal structure of the complex was first characterized by an X-ray crystallographic study, correcting the mistaken structural assignment of the complex in the literature. The results have demonstrated that the new family of ligands of the type Me4BPPy can act as pseudo-N-3 ligands to construct transition-metal catalysts.
关键词[WOS]: ASYMMETRIC TRANSFER HYDROGENATION ;  RUTHENIUM COMPLEXES ;  METAL-COMPLEXES ;  CATALYSTS ;  POLYMERIZATION ;  ETHYLENE ;  OLIGOMERIZATION ;  ACTIVATION ;  CHEMISTRY ;  ANALOGS
语种: 英语
WOS记录号: WOS:000231124400006
Citation statistics: 
内容类型: 期刊论文
URI标识: http://cas-ir.dicp.ac.cn/handle/321008/139843
Appears in Collections:中国科学院大连化学物理研究所_期刊论文

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作者单位: 1.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Peoples R China
2.Shenyang Pharmaceut Univ, Sch Pharmaceut Engn, Shenyang 110016, Peoples R China

Recommended Citation:
Deng, HX,Yu, ZK,Dong, JH,et al. 2,6-bis(3,5-dimethylpyrazol-1-yl)pyridine: A useful pseudo-N-3 ligand in efficient ruthenium(II)-catalyzed transfer hydrogenation of ketones[J]. ORGANOMETALLICS,2005,24(17):4110-4112.
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